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Synthesis and Structure of an o-Quinone Based Cuban Copper Complex with a Benzoxazole Substituent

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Abstract

A novel sterically hindered o-benzoquinone 4,6-di-tert-butyl-3-(5,7-di-tert-butylbenzooxazole-2-yl)-o-benzoquinone containing a benzoxazole moiety is prepared. The interaction of this quinone with Cu(0) yielded a cubane copper(II) complex with a Cu4O4 core. Molecular and crystal structures of the o-quinone (CCDC 2269708) and the copper complex (CCDC 2269709) are determined by XRD.

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Funding

The research was carried out at IOMC RAS using the of equipment the Analytical Center of IOMC RAS funded by the grant “Scientific Equipment for the Development of the Material and Technical Infrastructure of Common Use Centers” (unique identifier RF-2296.61321X0017, Agreement No. 075-15-2021-670).

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  1. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Nizhny Novgorod, Russia

    M. A. Zherebtsov, M. V. Arsenyev, E. V. Baranov & S. A. Chesnokov

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  2. M. V. Arsenyev
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  3. E. V. Baranov
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  4. S. A. Chesnokov
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Russian Text © The Author(s), 2023, published in Zhurnal Strukturnoi Khimii, 2023, Vol. 64, No. 11, 117710.https://doi.org/10.26902/JSC_id117710

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Zherebtsov, M.A., Arsenyev, M.V., Baranov, E.V. et al. Synthesis and Structure of an o-Quinone Based Cuban Copper Complex with a Benzoxazole Substituent. J Struct Chem 64, 2051–2062 (2023). https://doi.org/10.1134/S0022476623110033

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