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STUDY OF [Pd(NH3)4](MoO4)x(CrO4)1–x SOLID SOLUTIONS AND PRODUCTS OF THEIR THERMOLYSIS

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Abstract

By the single crystal X-ray diffraction (XRD) analysis it is shown that on slow co-crystallization of [Pd(NH3)4]MoO4 and [Pd(NH3)4]CrO4 salts, [Pd(NH3)4](MoO4)x(CrO4)1–x solid solutions with x ranging from 0.05 to 0.80 are formed. To construct the V(x) dependence an original procedure of refining unit cell parameters is used. It is revealed that in the thermal decomposition of the [Pd(NH3)4](MoO4)0.18(CrO4)0.82 single crystal (composition is determined by the single crystal XRD analysis) a mixture of phases based on the fcc lattice of Pd (Pd0.88Cr0.10Mo0.01) and on Cr2O3 is formed.

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REFERENCES

  1. A. I. Gubanov, S. A. Gromilov, S. V. Korenev, and A. B. Venediktov. J. Coord. Chem., 2001, 27(7), 537-539. https://doi.org/10.1023/A:1011393700721

    Article  CAS  Google Scholar 

  2. S. Korenev, A. Venediktov, Y. Shubin, S. Gromilov, and K. Yusenko. J. Struct. Chem., 2003, 44(1), 46-59. https://doi.org/10.1023/A:1024980930337

    Article  CAS  Google Scholar 

  3. A. A. Rybinskaya, P. E. Plyusnin, E. A. Bykova, S. A. Gromilov, Y. V. Shubin, and S. V. Korenev. J. Struct. Chem., 2012, 53(3), 527-533. https://doi.org/10.1134/S002247661203016X

    Article  CAS  Google Scholar 

  4. K. V. Yusenko, S. Khandarkhaeva, M. Bykov, T. Fedotenko, M. Hanfland, A. Sukhikh, and L. S. Dubrovinsky. Materials, 2020, 13(6), 1418. https://doi.org/10.3390/ma13061418

    Article  CAS  Google Scholar 

  5. E. Filatov, V. Lagunova, D. Potemkin, N. Kuratieva, A. Zadesenets, P. Plyusnin, A. Gubanov, and S. Korenev. Chem. Eur. J., 2020, 26(19), 4341-4349. https://doi.org/10.1002/chem.201905391

    Article  CAS  Google Scholar 

  6. P. S. Serebrennikova, V. Y. Komarov, A. S. Sukhikh, S. P. Khranenko, A. V. Zadesenets, S. A. Gromilov, and K. V. Yusenko. Nanomaterials, 2021, 11(12), 3272. https://doi.org/10.3390/nano11123272

    Article  CAS  Google Scholar 

  7. P. S. Serebrennikova, V. Y. Komarov, A. S. Sukhikh, and S. A. Gromilov. J. Struct. Chem., 2021, 62(5), 682-691. https://doi.org/10.1134/S0022476621050048

    Article  CAS  Google Scholar 

  8. P. S. Serebrennikova and S. A. Gromilov. J. Struct. Chem., 2022, 63(8), 1231-1241. https://doi.org/10.1134/S0022476622080042

    Article  CAS  Google Scholar 

  9. S. A. Gromilov. J. Struct. Chem., 2022, 63(6), 976-982. https://doi.org/10.1134/s0022476622060154

    Article  CAS  Google Scholar 

  10. Y. Laligant. Eur. J. Solid State Inorg. Chem., 1993, 30(10), 1017-1023.

  11. Y. Laligant. Eur. J. Solid State Inorg. Chem., 1993, 30(10), 681-688.

  12. A. I. Gubanov, E. Y. Filatov, E. Y. Semitut, A. I. Smolentsev, P. V. Snytnikov, D. I. Potemkin, and S. V. Korenev. Thermochim. Acta, 2013, 566, 100-104. https://doi.org/10.1016/j.tca.2013.03.036

    Article  CAS  Google Scholar 

  13. C. J. Lee, J. Park, J. M. Kim, Y. Huh, J. Y. Lee, and K. S. No. Chem. Phys. Lett., 2000, 327(5/6), 277-283. https://doi.org/10.1016/S0009-2614(00)00877-0

    Article  CAS  Google Scholar 

  14. J. Greeley and M. Mavrikakis. Catal. Today, 2006, 111, 52-58. https://doi.org/10.1016/j.cattod.2005.10.009

    Article  CAS  Google Scholar 

  15. X. Q. Zeng, Y. L. Wang, H. Deng, M. L. Latimer, Z. L. Xiao, J. Pearson, T. Xu, H. H. Wang, U. Welp, G. W. Crabtree, and W. K. Kwok. ACS Nano, 2011, 5(9), 7443-7452. https://doi.org/10.1021/nn2023717

    Article  CAS  Google Scholar 

  16. D.-B. Lee and G. Simkovich. J. Less-Common Metals, 1990, 163, 51-62. https://doi.org/10.1016/0022-5088(90)90085-X

    Article  CAS  Google Scholar 

  17. S. Diliberto, O. Kessler, C. Rapin, P. Steinmetz, and P. Berthod. J. Mater. Sci., 2002, 37(15), 3277-3284. https://doi.org/10.1023/A:1016191202525

    Article  CAS  Google Scholar 

  18. A. V. Alexeev and S. A. Gromilov. J. Struct. Chem., 2010, 51(4), 744-757. https://doi.org/10.1007/s10947-010-0110-3

    Article  CAS  Google Scholar 

  19. A. P. Hammersley. ESRF Internal Report, 1997, 68, 58.

  20. C. Prescher and V. B. Prakapenka. High Press. Res., 2015, 35, 223-230. https://doi.org/10.1080/08957959.2015.1059835

    Article  CAS  Google Scholar 

  21. Powder Diffraction File. PDF-2. International Centre for Diffraction Data, USA, 2021, https://www.icdd.com.

  22. OriginPro, OriginLab Corporation, Northampton, MA, USA, Version 2022b.

  23. APEX3 V.2019.1-0, SAINT V.8.40A and SADABS-V.2016/2. Madison, Wisconsin, USA: Bruker. AXS Inc., 2016-2019.

  24. M. Sheldrick. Acta Crystallogr., Sect. A: Found. Adv., 2015, 71, 3-8. https://doi.org/10.1107/S2053273314026370

    Article  Google Scholar 

  25. O. V. Dolomanov, L. J. Bourhis, R. J. Gildea, J. A. Howard, and H. Puschmann. J. Appl. Crystallogr., 2009, 42(2), 339-341. https://doi.org/10.1107/S0021889808042726

    Article  CAS  Google Scholar 

  26. V. I. Lysoivan. Izmerenie parametrov elementarnoi yacheyki na odnokristalnom spektrometre (Measurement of Unit Cell Parameters on a Single-Crystal Spectrometer). Novosibirsk, Russia: Nauka, 1982. [In Russian]

  27. Inorganic Crystal Structure Database. D-1754. Eggenstein-Leopoldshafen, Germany.

  28. W. Kraus and G. Nolze. J. Appl. Crystallogr., 1996, 29(3), 301-303. https://doi.org/10.1107/S0021889895014920

    Article  CAS  Google Scholar 

  29. K. V. Yusenko, E. Bykova, S. Riva, M. Bykov, W. A. Crichton, M. V. Yusenko, A. Sukhikh, S. Arnaboldi, M. Hanfland, L. S. Dubrovinsky, and S. A. Gromilov. Acta Mater., 2017, 139, 236-243. https://doi.org/10.1016/j.actamat.2017.08.012

    Article  CAS  Google Scholar 

  30. K. V. Yusenko, S. Riva, P. A. Carvalho, M. V. Yusenko, S. Arnaboldi, A. Sukhikh, M. Hanfland, and S. A. Gromilov. Scr. Mater., 2017, 138, 22-27. https://doi.org/10.1016/j.scriptamat.2017.05.022

    Article  CAS  Google Scholar 

  31. K. V. Yusenko, S. A. Martynova, S. Khandarkhaeva, T. Fedotenko, K. Glazyrin, E. Koemets, M. Bykov, A. Smekhova, K. Siemensmeyer, M. Hanfland, S. A. Gromilov, and L. S. Dubrovinsky. Materialia, 2020, 14, 100920. https://doi.org/10.1016/j.mtla.2020.100920

    Article  CAS  Google Scholar 

  32. G. Ghosh and G. B. Olson. J. Phase Equilib., 2000, 21(1), 32-39. https://doi.org/10.1361/105497100770340390

    Article  CAS  Google Scholar 

  33. E. N. Tupikova, I. A. Platonov, and T. N. Lykova. AIP Conf. Proc., 2016, 1724, 020052. https://doi.org/10.1063/1.4945172

    Article  Google Scholar 

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Funding

The work was supported by the Ministry of Science and Higher Education of the Russian Federation (project No. 121031700313-8) and Priority 2030.

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    P. S. Serebrennikova & S. A. Gromilov

  2. Novosibirsk State University, Novosibirsk, Russia

    P. S. Serebrennikova & S. A. Gromilov

Authors
  1. P. S. Serebrennikova
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  2. S. A. Gromilov
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Correspondence to P. S. Serebrennikova.

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Russian Text © The Author(s), 2022, published in Zhurnal Strukturnoi Khimii, 2022, Vol. 63, No. 11, 102106.https://doi.org/10.26902/JSC_id102106

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Serebrennikova, P.S., Gromilov, S.A. STUDY OF [Pd(NH3)4](MoO4)x(CrO4)1–x SOLID SOLUTIONS AND PRODUCTS OF THEIR THERMOLYSIS. J Struct Chem 63, 1856–1871 (2022). https://doi.org/10.1134/S0022476622110166

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