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TRIIODIDE SALTS OF 4-DIMETHYLAMINO- AND 3-BROMO-1-METHYLPYRIDINIUM: CRYSTAL STRUCTURES AND FEATURES OF NON-COVALENT I⋯I INTERACTIONS IN SOLIDS

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Abstract

Triiodide salts of pyridinium-derived cations of the composition CatI3 (Cat = 4-dimethylaminopyridinium (1), 3-bromo-1-methylpyridinium (2)) are prepared by reactions of respective cation iodide and I2 in the HI solution and characterized by single crystal XRD and Raman spectroscopy. The optical band gaps are calculated from the diffuse reflectance spectroscopy data.

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Funding

The work was supported by the RSF (project No. 18-73-10040) and the Ministry of Science and Higher Education of the Russian Federation (structural characterization of the samples, 121031700313-8).

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    N. A. Korobeinikov, A. N. Usoltsev, I. A. Shentseva, P. A. Abramov, I. V. Korolkov, P. E. Plusnin, B. A. Kolesov, M. N. Sokolov & S. A. Adonin

  2. Novosibirsk State University, Novosibirsk, Russia

    N. A. Korobeinikov & I. A. Shentseva

  3. Kazan (Volga region) Federal University, Kazan, Russia

    M. N. Sokolov

  4. South Ural State University, Chelyabinsk, Russia

    S. A. Adonin

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  1. N. A. Korobeinikov
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Russian Text © The Author(s), 2022, published in Zhurnal Strukturnoi Khimii, 2022, Vol. 63, No. 6, pp. 850-857.https://doi.org/10.26902/JSC_id95057

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Korobeinikov, N.A., Usoltsev, A.N., Shentseva, I.A. et al. TRIIODIDE SALTS OF 4-DIMETHYLAMINO- AND 3-BROMO-1-METHYLPYRIDINIUM: CRYSTAL STRUCTURES AND FEATURES OF NON-COVALENT I⋯I INTERACTIONS IN SOLIDS. J Struct Chem 63, 988–995 (2022). https://doi.org/10.1134/S0022476622060178

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