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Crystal Structure of New One-Dimensional Triple Molybdate Na2K2Cu(MoO4)3

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Abstract

The title compound (disodium dipotassium copper(II) tris-[molybdate (VI)]) is prepared by form melt and characterized by single crystal X-ray diffraction and UV-vis spectroscopy. It crystallizes in the triclinic space group P-1 with a = 7.4946(8) Å, b = 9.3428(9) Å, c = 9.3619(9) Å, α = 92.591(7)°, β = 105.247(9)°, γ = 105.496(9)°, V = 604.7 Å3, and Z = 2. Its structure is isotypic with that of Na4Mn(MoO4)3. It is formed by Cu2O10 distorted bi-octahedral dimers linked by two bridging bidentate Mo2O4 tetrahedra and, additionally, two monodentate Mo1O4 tetrahedra to form Cu2Mo4O20 units. These units are linked by the insertion of Mo3O4 tetrahedra to build infinite ribbons disposed along the c axis. All of these ribbons form a one-dimensional framework. Both K1 and K3 cations are located in the inversion center, and all the other atoms are at general positions. The structure model is supported by the bond valence sum (BVS) and charge distribution CHARDI methods. The Cu2+ cations adopt the [4+2] CuO6 Jahn-Teller distortion giving rise to an intense d–d transition in the UV-vis absorption spectra.

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References

  1. B. G. Bazarov, R. F. Klevtsova, A. D. Tsyrendorzhieva, L. A. Glinaskaya, and Zh. G. Bazarova. J. Struct. Chem., 2004, 45(6), 993–998.

    Google Scholar 

  2. N. I. Sorokin. Phys. Solid State., 2009, 51, 1128–1130.

    Article  CAS  Google Scholar 

  3. Y. Zhang, H. Cong, H. Jiang, J. Li, and J. Wang. J. Cryst. Growth., 2015, 423, 1–8.

    Article  CAS  Google Scholar 

  4. A. Kato, S. Oishi, T. Shishido, M. Yamazaki, and S. Iida. J. Phys. Chem. Solids., 2005, 66, 2079–2081.

    Article  CAS  Google Scholar 

  5. N. M. Kozhevnikova and O. A. Kopylova. Russ. J. Inorg. Chem., 2011, 56, 935–938.

    Article  CAS  Google Scholar 

  6. A. E. Sarapulova, B. Bazarov, T. Namsaraeva, S. Dorzhieva, J. Bazarova, V. Grossman, A. A. Bush, I. Antonyshyn, M. Schmidt, A. M. T. Bell, M. Knapp, H. Ehrenberg, J. Eckert, and D. Mikhailova. J. Phys. Chem. C., 2014, 118, 1763–1773.

    Article  CAS  Google Scholar 

  7. Y. S. Yoon, W. Ueda, and Y. Moro–oka. Top Catal., 1996, 3, 265–275.

    Article  CAS  Google Scholar 

  8. J. D. Pless, B. B. Bardin, H.–S. Kim, D. Ko, M. T. Smith, R. R. Hammond, P. C. Stair, and K. R. Poeppelmeier. 2004, J. Catal., 223, 419–431.

    Google Scholar 

  9. W. Ueda, Y.–S. Yoon, K.–H. Lee, and Y. Moro–oka. Korean J. Chem. Eng., 1997, 14, 474–478.

    Article  CAS  Google Scholar 

  10. M. Nowak, B. Kauch, and P. Szperlich. Rev. Sci. Instrum., 2009, 80, 046107.

    Article  CAS  PubMed  Google Scholar 

  11. G. M. Sheldrick. Acta Crystallogr., 2008, A64, 112–122.

    Google Scholar 

  12. L. J. Farrugia. J. Appl. Crystallogr., 2012, 45, 849–854.

    Article  CAS  Google Scholar 

  13. S. F. Solodovnikov, P. V. Klevtsov, Z. A. Solodovnikova, L. A. Glinskaya, and R. F. Klevtsova. J. Struct. Chem., 1998, 39(2), 230–237.

    Google Scholar 

  14. G. D. Tsyrenova, S. F. Solodovnikov, E. G. Khaikina, E. T. Khobrakova, Zh. G. Bazarova, and Z. A. Solodovnikova. J. Solid. State. Chem., 2004, 177, 2158–2167.

    Article  CAS  Google Scholar 

  15. B. Murphy and B. Hathaway. Coord. Chem. Rev., 2003, 243, 237–262.

    Article  CAS  Google Scholar 

  16. H. Effenberger. Monatsh Chem., 1988, 119, 1103–1112.

    Article  CAS  Google Scholar 

  17. Y. Senga and A. Kawahara. Acta Crystallogr., 1980, B36, 2555–2558.

    Google Scholar 

  18. G. D. Tsyrenova, S. F. Solodovnikov, E. T. Pavlova, E. G. Khaikina, and Z. A. Solodovnikova. Russ. J. Inorg. Chem., 2009, 54(5), 743–750.

    Google Scholar 

  19. K. Kawamura, A. Kawahara, and J. Iiyama. Acta Crystallogr., 1978, B34, 3181–3185.

    Google Scholar 

  20. S. Adams. SoftBV. Version 0.96. University of Göttingen, Germany, 2004.

    Google Scholar 

  21. M. Nespolo. CHARDT–IT, CRM2. University Henri Poincaré Nancy I, France, 2001.

    Google Scholar 

  22. M. Nespolo, G. Ferraris, G. Ivaldi, and R. Hoppe. Acta Crystallogr., 2001, B57, 652–664.

    Google Scholar 

  23. L. J. Pauling. J. Am. Chem. Soc., 1929, 51, 1010–1026.

    Article  CAS  Google Scholar 

  24. M. Ulutagay–Kartin, S.–J. Hwu, and J. A. Clayhold. Inorg. Chem., 2003, 42, 2405–2409.

    Article  CAS  PubMed  Google Scholar 

  25. P. Adler, A. Breitschwerdt, H.–U. Habermeier, G. Mertens, and A. Simon. J. Struct. Chem., 1990, 87, 141–151.

    CAS  Google Scholar 

Download references

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  1. Université de Tunis El Manar, Faculté des Sciences, Laboratoire de Matériaux, Cristallochimie et Thermodynamique Appliquée, Tunis, Tunisie

    W. Dridi & M. F. Zid

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  1. W. Dridi
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  2. M. F. Zid
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Correspondence to W. Dridi.

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Original Russian Text © 2018 W. Dridi, M. F. Zid.

The text was submitted by the authors in English. Zhurnal Strukturnoi Khimii, Vol. 59, No. 5, pp. 1168–1172, June-July, 2018.

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Dridi, W., Zid, M.F. Crystal Structure of New One-Dimensional Triple Molybdate Na2K2Cu(MoO4)3. J Struct Chem 59, 1128–1132 (2018). https://doi.org/10.1134/S0022476618050153

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