Abstract
Three new complexes [Cd(Hflu)2(NO3)](NO3) 1, [Cd(H2O)(Hflu)2(Hmalo)](NO3)∙2(H2O) 2, and [Cd(H2O)(Hflu)2(Hfum)](NO3)∙2(H2O) 3 (Hflu = [2-(2,4-difluorophenyl)-1,3-bis(1,2,4-triazol-1-yl)-propan-2-ol], H2fum = fumaric acid, H2malo = malonate acid) are synthesized by a solution diffusion method and characterized by single crystal X-ray diffraction methods, elemental analyses, IR spectroscopy as well as thermal analyses. In compound 1, Cd(II) cations are bridged by fluconazole ligands to form 2D Cd−Hflu layers, and these layers are further connected by C–H∙∙∙F hydrogen bonds to form a complicated 3D structure with the topology of (4∙6∙8)(4∙64∙84∙10)(6∙3). Compounds 2 and 3 are isostructural, and in them the Cd(II) cations are bridged by fluconazole ligands to form a 2D network, which is connected by C–H∙∙∙O hydrogen bonds to form a complicated 3D (3,4)-connected framework with the topology of (4∙82)(4∙85).
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
A. Corma, F. Rey, J. Rius, M. J. Sabater, and S. Valencia, Nature, 431, 287–290 (2004).
W. Schmitt, E. Baissa, A. Mandel, C. E. Anson, and A. K. Powell, Angew. Chem., Int. Ed., 40, No. 19, 3577–3581 (2001).
P. Sozzani, S. Bracco, A. Comotti, L. Ferretti, and R. Simonutti, Angew. Chem., Int. Ed., 44, No. 12, 1816–1820 (2005).
S. Campidelli, T. Brandmüller, A. Hirsch, I. M. Saez, J. W. Goodby, and R. Deschenaux, Chem. Commun., 4282–4284 (2006).
A. Petitjean, F. Puntoriero, S. Campagna, A. Juris, and J. M. Lehn, Eur. J. Inorg. Chem., 3878–3892 (2006).
C. Janiak, Dalton Trans., 2781–2804 (2003).
R. G. Xiong, J. L. Zuo, X. Z. You, B. F. Abrahams, Z. P. Bai, C. M. Che, and H. K. Fun, Chem. Commun., 2061/2062 (2000).
X. L. Wang, C. Qin, E. B. Wang, L. Xu, Z. M. Su, and C. W. Hu, Angew. Chem., 116, 5146–5150 (2004).
G. O. Lloyd, J. L. Atwood, and L. J. Barbour, Chem. Commun., 1845–1847 (2005).
R. Carballo, B. Covelo, M. S. E. Fallah, J. Ribas, and E. M. Vazquez-Lopez, Cryst. Growth Des., 7, 1069–1077 (2007).
R. Y. Li, X. Y. Wang, T. Liu, H. B. Xu, F. Zhao, Z. M. Wang, and S. Gao, Inorg. Chem., 47, 8134–8142 (2008).
U. G. Couceiro, O. Castillo, A. Luque, J. P. G. Teran, G. Beobide, and P. Roman, Cryst. Growth Des., 6, 1839–1847 (2006).
T. K. Maji, R. Matsuda, and S. Kitagawa, Nat. Mater., 6,142–148 (2007).
J. P. Zhang and X. M. Chen, J. Am. Chem. Soc., 130, 6010–6017 (2008).
P. S. Mukherjee, S. Konar, E. Zangrando, T. Mallah, J. Ribas, and N. R. Chaudhuri. Inorg. Chem., 42, 2695–2703 (2003).
M. C. Suen, Z. K. Chan, J. D. Chen, J. C. Wang, and C. H. Hung. Polyhedron, 25, No. 11, 2325–2332 (2006).
L. J. Su, H. Y. Zang, H. S. Liu, L. M. Wang, W. H. Li, and Z. M. Su, Inorg. Chem. Commun., 13, 981 (2010).
H. W. Roesky and M. Andruh, Coord. Chem. Rev., 236, 91 (2003).
S. Kitagawa and K. Uemura, Chem. Soc. Rev., 34, 109 (2005).
H. M. Keizer and R. P. Sijbesma, Chem. Soc. Rev., 34, 226 (2005).
G. M. Sheldrick, SHELXS-97, Program for Crystal Structure Solution, University of Göttingen, Germany (1997).
G. M. Sheldrick, SHELXL-97, Program for Crystal Structure Refinement, University of Göttingen, Germany (1997).
X. J. Luan, X. H. Cai, Y. Y. Wang, D. S. Li, C. J. Wang, P. Liu, H. M. Hu, Q. Z. Shi, and S. M. Peng, Chem. Eur. J., 12, 6281 (2006).
R. Wang, M. Hong, J. Luo, R. Cao, and J. Weng, Chem. Commun., 1018 (2003).
K. Nakamoto, Infrared and Raman Spectra of Inorganic and Coordination Compounds, 4th ed., Interscience-Wiley, New York (1986).
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © 2016 C.-J. Lin, L.-X. Zhou, Q.-J. Niu, Y.-Q. Zheng, H.-L. Zhu, B.-B. Zhang.
Rights and permissions
About this article
Cite this article
Lin, CJ., Zhou, LX., Niu, QJ. et al. Three metal-organic polymers assembled from Cd(II)–fluconazole: Syntheses, crystal structures, and characterization. J Struct Chem 57, 155–166 (2016). https://doi.org/10.1134/S0022476616010194
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0022476616010194