Skip to main content
SpringerLink
Log in

Conductance of aqueous sodium decyl sulfate solutions and the nature of hydration of the decyl sulfate anion

  • Published:
Journal of Structural Chemistry Aims and scope Submit manuscript

Abstract

A study is made of the temperature and concentration dependences for conductance of aqueous sodium decyl sulfate solutions. The nature of hydration of the decyl sulfate anion is discussed within the theories proposed by Samoilov, Gurikov, and Krestov. An analysis is performed of the influence of the hydration type on the critical micelle concentration. The analysis suggests that an increase in temperature stimulates micelle formation given that hydration is negative.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. A. I. Rusanov, Micelle Formation in Solutions of Surface-Active Agents [in Russian], Khimiya, St. Petersburg (1997).

    Google Scholar 

  2. V. K. Abrosimov, J. Struct. Chem., 14, No. 2, 193–196 (1973).

    Article  Google Scholar 

  3. R. K. Mazitov, Dokl. Akad. Nauk SSSR, 260, No. 6, 1402–1407 (1981).

    CAS  Google Scholar 

  4. M. N. Rodnikova, S. A. Zasypkin, and G. G. Malenkov, Zh. Fiz. Khim., 324, No. 2, 368–372 (1992).

    CAS  Google Scholar 

  5. L. T. Vlaev, S. D. Genieva, and M. P. Tavlieva, J. Struct. Chem., 44, No. 6, 995–1000 (2003).

    Article  CAS  Google Scholar 

  6. E. V. Butyrskaya, V. A. Shaposhnik, and A. M. Butyrskii, Vestn. Voronezh. Gos. Univ., Ser. Khim., Biol., Farm., No. 2, 25–27 (2004).

    Google Scholar 

  7. A. Yu. Vlasov, K. R. Savchuk, A. A. Starikova, and N. A. Smirnova, Zhidk. Krist. Ikh Prakt. Ispol’z, 4, No. 38, 90–102 (2011).

    Google Scholar 

  8. N. N. Kochurova, K. N. Surkov, and A. I. Rusanov, Zh. Obshch. Khim., 65, No. 8, 1276–1278 (1995).

    CAS  Google Scholar 

  9. V. I. Yashkichev and Yu. M. Dergachev, Zh. Fiz. Khim., 66, No. 5, 1252–1256 (1992).

    CAS  Google Scholar 

  10. R. D. Oparin, M. V. Fedotova, and V. N. Trostin, J. Struct. Chem., 43, No. 3, 467–472 (2002).

    Article  CAS  Google Scholar 

  11. Ya. Samoilov, Structure of Aqueous Electrolyte Solutions and Ion Hydration [in Russian], Akad. Nauk SSSR, Moscow (1957).

    Google Scholar 

  12. Yu. V. Gurikov, Zh. Fiz. Khim., 66, No. 5, 1257–1262 (1992).

    CAS  Google Scholar 

  13. G. A. Krestov, Thermodynamics of Ionic Processes in Solutions [in Russian], Khimiya, Leningrad (1984).

    Google Scholar 

  14. M. N. Rodnikova and N. A. Chumaevskii, J. Struct. Chem., 47, S151–S158 (2006).

    Article  CAS  Google Scholar 

  15. N. F. Bunkin and F. V. Bunkin, J. Phys. Water Phenom., 21, No. 2, 81–109 (2013).

    Article  Google Scholar 

  16. M. Yu. Pletnev, Surfactant Compounds and Compositions: Reference Book [in Russian], Moscow (2002).

    Google Scholar 

  17. A. A. Abramzon, L. P. Zaichenko, and S. I. Faingol’d, Surfactants: Reference Book [in Russian], Khimiya, Leningrad (1988).

    Google Scholar 

  18. A. A. Abrosimov, V. V. Korolev, V. N. Afanas’ev, et al., Experimental Methods in Solution Chemistry: Densitometry, Viscometry, Conductometry, and Other Methods. Series: Problems of Solution Chemistry [in Russian], Nauka, Moscow (1997).

    Google Scholar 

  19. S. Durand-Vidal, P. Turq, and O. Bernad, J. Phys. Chem., 100, No. 43, 17345–17350 (1996).

    Article  CAS  Google Scholar 

  20. Z. N. Markina, L. P. Panicheva, and N. M. Zadymova, Kolloidn. Zh., 59, No. 3, 341–349 (1997).

    Google Scholar 

  21. A. A. Ravdel’ and A. M. Ponomareva, A Short Guide on Physicochemical Values [in Russian], Khimiya, Leningrad (1983).

    Google Scholar 

  22. T. Erdey-Grúz, Transport Phenomena in Aqueous Solutions, Hilger, London (1974).

    Google Scholar 

  23. Yu. M. Kessler and A. L. Zaitsev, Solvophobic Effects [in Russian], Khimiya, Leningrad (1989).

    Google Scholar 

  24. V. A. Tyurin and A. I. Maklakov, Strukt. Din. Mol. Sist., No. 3, 105–109 (2003).

    Google Scholar 

  25. V. I. Bulavin, I. N. V’yunnik, and A. E. Savis’ko, Vestn. Khark. Nats. Univ., 22 (45), No. 1085, 156–167 (2013).

    Google Scholar 

  26. T. Mehrian, A. de Keizer, A. J. Kortewegand, and J. Lyklema, Colloids Surf., A, 71, 255–267 (1993).

    Article  CAS  Google Scholar 

  27. K. N. Surkov and N. N. Kochurova, Fiz. Khim. Rastvorov, 68, No. 4, 642–644 (1994).

    CAS  Google Scholar 

  28. T. L. Smirnov and N. N. Kochurova, Kolloidn. Zh., 63, No. 1, 123–126 (2001).

    Google Scholar 

  29. T. L. Smirnov and N. N. Kochurova, Vestn. S.-Peterb. Univ., 4 (1), No. 3, 97–100 (2001).

    Google Scholar 

  30. T. L. Smirnov and N. N. Kochurova, Zh. Fiz. Khim., 78, No. 7, 1250–1253 (2004).

    CAS  Google Scholar 

  31. O. P. Korotkikh and N. N. Kochurova, Zh. Prikl. Khim., 79, No. 7, 1214–1216 (2006).

    Google Scholar 

  32. O. P. Korotkikh and N. N. Kochurova, J. Phys. Chem. A, 81, No. 7, 1059–1061 (2007).

    CAS  Google Scholar 

  33. M. H. Ropers, G. Czichocki, and G. Brezesinski, J. Phys. Chem. B, 107, No. 22, 5281–5288 (2003).

    Article  CAS  Google Scholar 

  34. O. P. Korotkikh, N. N. Kochurova, and Hong Po-Da, Mendeleev Commun., No. 18, 347–349 (2008).

    Article  CAS  Google Scholar 

  35. S. Bhatacharya and J. Haldar, Langmuir, 2005, 21, No. 13, 5747–5751 (2008).

    Google Scholar 

  36. Y. A. Ershov, J. Phys. Chem. A, 83, No. 10, 1661–1664 (2009).

    CAS  Google Scholar 

  37. Yu. M. Kessler, V. E. Petrenko, A. Ya. Lyashchenko, et al., Water: Structure, State, Solvation [in Russian], Nauka, Moscow (2003).

    Google Scholar 

  38. J. M. del Rio and M. N. Jones, J. Phys. Chem. B, 105, No. 6, 1200–1211 (2001).

    Article  Google Scholar 

  39. G. N. Sarkisov, Usp. Fiz. Nauk, 176, No. 8, 833–845 (2006).

    Article  Google Scholar 

  40. R. C. Reid, J. M. Prausnitz, and T. K. Sherwood, The Properties of Gases and Liquids, McGraw-Hill, New-York (1977).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Chemistry, St. Petersburg State University, St. Petersburg, Russia

    O. P. Korotkikh, N. N. Kochurova & T. N. Kozlova

Authors
  1. O. P. Korotkikh
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. N. N. Kochurova
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. T. N. Kozlova
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to O. P. Korotkikh.

Additional information

Original Russian Text © 2015 O. P. Korotkikh, N. N. Kochurova, T. N. Kozlova.

Translated from Zhurnal Strukturnoi Khimii, Vol. 56, No. 6, pp. 1149–1155, November–December, 2015.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Korotkikh, O.P., Kochurova, N.N. & Kozlova, T.N. Conductance of aqueous sodium decyl sulfate solutions and the nature of hydration of the decyl sulfate anion. J Struct Chem 56, 1097–1103 (2015). https://doi.org/10.1134/S0022476615060116

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0022476615060116

Keywords

Search

Navigation