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Crystal structure and luminescent properties of a one-dimensional Cd(II) coordination polymer constructed by 4,4′-di-tert-butyl-2,2′-bipyridine and 5-tert-butyl isophthalic acid

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Abstract

A one-dimensional Cd(II) complex [Cd(Bu2bpy)(tbip)∙ H2O] n (1) (Bu2bpy = 4,4′-di-tert-butyl-2,2′- bipyridine, H2tbip = 5-tert-butyl isophthalic acid) is synthesized and characterized using single crystal X-ray diffraction, IR spectroscopy, and elemental analysis. The single crystal X-ray diffraction analysis reveals that complex 1 is a one-dimensional double chain polymer based on {Cd2(OCO)2} dimeric kernels with a Cd...Cd separation of 4.3197(7) Å. The thermal stability and luminescent properties of the title complex are briefly investigated.

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Authors and Affiliations

  1. Department of Chemistry, Yancheng Teachers University, Yancheng, Jiangsu, P. R. China

    X. J. Xu & J. Wang

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  1. X. J. Xu
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  2. J. Wang
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Correspondence to X. J. Xu.

Additional information

The text was submitted by the authors in English. Zhurnal Strukturnoi Khimii, Vol. 56, No. 4, pp. 831-835, July-August, 2015. Original article submitted November 25, 2013.

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Xu, X.J., Wang, J. Crystal structure and luminescent properties of a one-dimensional Cd(II) coordination polymer constructed by 4,4′-di-tert-butyl-2,2′-bipyridine and 5-tert-butyl isophthalic acid. J Struct Chem 56, 782–786 (2015). https://doi.org/10.1134/S0022476615040277

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  • DOI: https://doi.org/10.1134/S0022476615040277

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