Abstract
It is found that diffraction patterns of complexes I–V of the composition [Ln(Phen)(C4H8NCS2)3] (Ln = Sm, Eu, Tb, Dy, and Tm respectively) are similar. Single crystals of [Dy(Phen)(C4H8NCS2)3]·3CH2Cl2 (VI) obtained are. According to the X-ray crystallographic data, in the structure of VI the unit cell contains two crystallographically independent molecules of the [Dy(Phen)(C4H8NCS2)3] complex and six CH2Cl2 molecules. The N2S6 coordination polyhedron of the Dy atom is a distorted square antiprism. In the range of 2–300 K the magnetic properties of complexes I–V are studied. It is found that complex III passes to the magnetically ordered state; the spontaneous magnetization at 2 K is 24 600 G·cm3/mol. At 300 K compounds I–IV exhibit photoluminescence in the visible spectral range. It is found that the photoluminescence intensity of complex I is several times higher than the photoluminescence intensity of complexes II–IV.
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References
G. F. De Sa, O. L. Malta, C. de Mello Donega, et al., Coord. Chem. Rev., 196, 165–195 (2000).
J.-C. G. Bünzli, Acc. Chem. Res., 39, 53–61 (2006).
A. V. Metelitsa, A. S. Burlov, S. O. Bezuglyi, et al., Koord. Khim., 32, No. 12, 858–868 (2006).
L. Armelao, S. Quici, E. Barigelletti, et al., Coord. Chem. Rev., 254, 487–505 (2010).
M. N. Bochkarev, A. G. Vitukhnovskii, and M. A. Katkova, Organic Light Emitting Diodes (OLED) [in Russian], Dekom, Nizhni Novgorod (2011).
M. A. Katkova, A. V. Borisov, G. K. Fukin, et al., Inorg. Chim. Acta, 359, No. 13, 4289–4296 (2006).
T. Kobayashi, H. Naruke, and T. Yamase, Chem. Lett., No. 9, 907/908 (1997).
C. G. Su, M. Y. Tan, N. Tang, et al., J. Coord. Chem., 38, No. 3, 207–218 (1996).
V. L. Varand, L. A. Glinskaya, R. F. Klevtsova, and S. V. Larionov, J. Struct. Chem., 39, No. 2, 344–352 (1998).
W. M. Faustino, O. L. Malta, E. E. S. Teotonio, et al., J. Phys. Chem. A, 110, 2510–2516 (2006).
M. D. Regulacio, M. H. Publico, J. A. Vasquez, et al., Inorg. Chem., 47, No. 5, 1512–1523 (2008).
X.-X. Meng, S.-L. Gao, S.-P. Chen, et al., Acta Chim. Sinica, 62, No. 22, 2233–2238 (2004).
S. P. Chen, X. X. Meng, Q. Shuai, et al., J. Therm. Anal. Cal., 86, No. 3, 767–774 (2006).
S. P. Chen, S. L. Gao, X. W. Yang, et al. Russ. J. Cord. Chem., 33, No. 3, 231–238 (2007).
G. M. Sheldrick, Acta Crystallogr. A, 64, No. 1, 112–122 (2008).
C. A. Hanter and J. K. M. Sanders, J. Am. Chem. Soc., 112, No. 14, 5525–5534 (1990).
S. Cotton, Lanthanide and Actinide Chemistry, John Wiley and Sons, Chichester (2006).
M. Latva, H. Takalo, V.-M. Mukkala, et al., J. Luminescence, 75, No. 2, 149–169 (1997).
S. V. Larionov, A. A. Voityuk, L. N. Mazalov, et al., Izv. Akad. Nauk SSSR, Ser. Khim., No. 5, 998–1002 (1985).
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Original Russian Text © 2014 Yu. A. Bryleva, L. A. Glinskaya, I. V. Korol’kov, A. S. Bogomyakov, M. I. Rakhmanova, D. Yu. Naumov, T. E. Kokina, S. V. Larionov.
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Translated from Zhurnal Strukturnoi Khimii, Vol. 55, No. 2, pp. 339–347, March–April, 2014.
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Bryleva, Y.A., Glinskaya, L.A., Korol’kov, I.V. et al. Structure of [Dy(Phen)(C4H8NCS2)3]·3CH2Cl2 solvate. Magnetic properties and photoluminiscence of [Ln(Phen)(C4H8NCS2)3] (Ln = Sm, Eu, Tb, Dy, Tm) complexes. J Struct Chem 55, 319–326 (2014). https://doi.org/10.1134/S002247661402019X
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DOI: https://doi.org/10.1134/S002247661402019X