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Ion-molecular interactions in the metalloporphyrin-acid system in liquid solutions

  • Proceedings of the 16th Symposium on Intermolecular Interactions and Conformations of Molecules June 18–22, 2012, Ivanovo
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Abstract

A new form of MP...H +solv metalloporphyrins is found and studied in the strong acid medium, the conditions of its formation and the qualitative reaction of its determination are established. It is shown that the same form has the H4TPP2+ dication (TPP is the 5,10,15,20-tetraphenyl-21H,23H-porphyrine dianion). The stability in different acid media and in the isolated state, spectral properties and the structure of H+-associates of porphyrins are analyzed in detail by UV-visible and 1H NMR spectroscopy and quantum chemical calculations. It is shown that they have a unique two-band visible electronic spectrum with the bands near 540 nm and 700 nm, which weakly depend on the type of the central atom in the complex and noticeably change when the chromophore is functionally substituted. The proton location the ion-molecular associate and the cases of the formation of H+-associates with higher stoichiometry are revealed.

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References

  1. P. A. Stuzhin, J. Porphyrins Phthalocyanines, 7, No. 12, 813 (2003).

    Article  CAS  Google Scholar 

  2. B. D. Berezin and V. G. Andrianov, Izv. Vyssh. Uchebn. Zveden., Ser. Khim. Tekhnol., 20, No. 6, 807 (1977).

    CAS  Google Scholar 

  3. V. G. Andrianov, O. V. Malkova, and B. D. Berezin, in: Advances in Chemistry of Porphyrins [in Russian], O. A. Golubchikov (ed.), 3, Izd. NII Khimii SPbGU, St. Petersburg (2001) p. 107.

  4. H. R. Jimenez, M. Jolve, and J. Faus, J. Chem. Soc., Dalton Trans.: Inorg. Chem., 19991, No. 8, 1945 (1972–1999).

    Google Scholar 

  5. P. A. Stuzhin, A. A. Gaberkorn, O. V. Molodkina, and I. Pimkov, Abstr. of 2nd Internat. Conf. on Porphyrins and Phthalocyanines ICPP-2, P-78, 326, Kyoto, (2002).

    Google Scholar 

  6. E. E. Suslova and T. N. Lomova, Rus. J. Coordinats. Chem., 32, No. 3, 155 (2006).

    Article  CAS  Google Scholar 

  7. T. N. Lomova and T. N. Sokolova, in: Advances in Chemistry of Porphyrins [in Russian], O. A. Golubchikov (ed.), Izd. NII Khimii SPbGU, 2, St. Petersburg (1999), p. 167.

    Google Scholar 

  8. T. N. Sokolova, E. E. Suslova, T. N. Lomova, S. V. Zaitseva, and S. A. Zdanovich, Rus. J. Inorg. Chem., 47, No. 9, 1333 (2002).

    Google Scholar 

  9. K. Schweiger, H. Hükstädt, and H. Homborg, Z. Naturforsch., B54, 963 (1999).

    Google Scholar 

  10. C.-H. Tsai, J.-Y. Tung, J.-H. Chen, F.-L. Liao, S.-L. Wang, S.-S. Wang, L.-P. Hwang, and C.-B. Chen, Polyhedron, 19, 633 (2000).

    Article  CAS  Google Scholar 

  11. L. Jaguinod, R. G. Khoyri, and K. M. Smith, Chem. Commun., 1261 (1998).

    Google Scholar 

  12. N. N. Kruk, A. S. Staruchin, N. Zh. Mamardashvili, V. B. Sheinin, and Yu. B. Ivanova, J. Appl. Spectroscopy, 74, No. 6, 831 (2007).

    Article  CAS  Google Scholar 

  13. T. N. Lomova, E. G. Mozhzhukhina, L. P. Shormanova, and B. D. Berezin, Zh. Obshch. Khim., 59, 2317 (1989).

    CAS  Google Scholar 

  14. V. V. Morozov, Synthesis and Physicochemical Study of Tetraphenylporphyrin Sulfo Derivatives [in Russian], Diss. ... Cand. of Chem. Sc., Institute of Chemical Technology, Ivanovo (1983).

    Google Scholar 

  15. T. N. Lomova, in: Advances in Chemistry of Porphyrins [in Russian], O. A. Golubchikov (ed.), Izd. NII Khimii SPbGU, 3, St. Petersburg (2001), p. 233.

    Google Scholar 

  16. T. N. Lomova and B. D. Berezin, Koordinats. Khim., 19, 171 (1993).

    CAS  Google Scholar 

  17. T. N. Lomova, E. G. Mozhzhukhina, and B. D. Berezin, Zh. Neorg. Khim., 38. No. 9, 1552 (1993).

    Google Scholar 

  18. T. N. Lomova and E. G. Mozhzhukhina, Zh. Neorg. Khim., 42, No. 10, 1691 (1997).

    CAS  Google Scholar 

  19. T. N. Lomova, E. Yu. Tyulyaeva, and E. G. Mozhzhuhina, Russ. J. Coord. Chem., 29, No. 8, 564 (2003).

    Article  Google Scholar 

  20. T. N. Lomova and E. G. Mozhzhukhina, Russ. J. Inorg. Chem., 57, No. 2, 197 (2012).

    Article  CAS  Google Scholar 

  21. T. N. Lomova, E. Yu. Tyulyaeva, and L. G. Andrianova, Russ. J. Inorg. Chem., 46, No. 3, 371 (2001).

    Google Scholar 

  22. T. N. Lomova and E. Yu. Tyulyaeva, Russ. J. Coord. Chem., 27, No. 6, 433 (2001).

    Article  Google Scholar 

  23. A. S. Semeikin, Proc. of the 29th Russ. Workshop on Chemistry of Porphyrins and Their Analogs [in Russian], Ivanovo (2006).

    Google Scholar 

  24. J. W. Buchler and C. Dreher, Z. Naturforsch., 39b, 222 (1982).

    Google Scholar 

  25. P. A. Stuzhin, E. V. Fedotova, N. V. Repina, and M. E. Klyueva, Rus. J. Phys. Chem. A, 78, No. 6, 864 (2004).

    Google Scholar 

  26. J. J. P. Stewart, J. Comput. Chem., 10, 209 (1989).

    Article  CAS  Google Scholar 

  27. R. Fletcher, Methods of Optimization, John Wiley & Sons, New York (1980).

    Google Scholar 

  28. J. J. P. Stewart, J. Computer-Aided Molecular Desing, 4, 1 (1990).

    Article  Google Scholar 

  29. W. P. Anderson, W. D. Edwards, and M. C. Zerner, Inorg. Chem., 25(16), 2728 (1986).

    Article  CAS  Google Scholar 

  30. J. Mack and M. J. Stillman, J. Porphyrins Phthalocyanines, 5, No. 1, 67 (2001).

    Article  CAS  Google Scholar 

  31. R. P. Bell, The Proton in Chemistry, Chapman and Hall, London (1973).

    Book  Google Scholar 

  32. J. S. Dewar and K. M. Dieter, J. Am. Chem. Soc., 108, 8075 (1986).

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. G. A. Krestov Institute of Solution Chemistry, Russian Academy of Sciences, Ivanovo, Russia

    T. N. Lomova, E. G. Mozhzhukhina, E. Yu. Tyulyaeva, N. G. Bichan, S. V. Zaitseva & S. A. Zdanovich

  2. Ivanovo State Medical Academy, Ivanovo, Russia

    M. E. Klyueva

Authors
  1. T. N. Lomova
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  2. M. E. Klyueva
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  3. E. G. Mozhzhukhina
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  4. E. Yu. Tyulyaeva
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  5. N. G. Bichan
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  6. S. V. Zaitseva
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  7. S. A. Zdanovich
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Correspondence to T. N. Lomova.

Additional information

Original Russian Text © 2014 T. N. Lomova, M. E. Klyueva, E. G. Mozhzhukhina, E. Yu. Tyulyaeva, N. G. Bichan, S. V. Zaitseva, S. A. Zdanovich.

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Translated from Zhurnal Strukturnoi Khimii, Vol. 55, No. 1, pp. 186–197, January–February, 2014.

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Lomova, T.N., Klyueva, M.E., Mozhzhukhina, E.G. et al. Ion-molecular interactions in the metalloporphyrin-acid system in liquid solutions. J Struct Chem 55, 180–190 (2014). https://doi.org/10.1134/S0022476614010314

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  • DOI: https://doi.org/10.1134/S0022476614010314

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