Abstract
Equilibrium processes in the (rhodium-graphene islands) system have been studied. It has been shown that the critical degree of carbon coating ϑcr in the chemisorbed “gas” phase on the surface is significantly different from the equilibrium degree of coating ϑeq. When ϑcr is reached, a phase transition occurs and graphene islands are nucleated, whereas graphene islands with different relative areas are in equilibrium at ϑeq with chemisorbed carbon gas; these degrees of coating are related as ϑeq > ϑcr. This effect occurs for metals dissolving carbon in the bulk and is explained by the dominating role of the perimeter of islands through which exchange of atoms between islands and carbon gas occurs.
Similar content being viewed by others
References
K. S. Novoselov, Rev. Mod. Phys. 83, 837 (2011).
A. K. Geim, Rev. Mod. Phys. 83, 851 (2011).
A. M. Shikin, V. K. Adamchuk, and K. H. Rieder, Phys. Solid State 51, 2390 (2009).
M. Losurdo, M. M. Giangregorio, and G. Bruno, Phys. Chem. Chem. Phys. 13, 20836 (2011).
X. Chen, L. Zhang, and S. Chen, Synth. Met. 210, 95 (2015).
E. Grånäs, J. Knudsen, U. A. Schröder, T. Gerber, C. Busse, M. A. Arman, K. Schulte, J. N. Andersen, and T. Michely, ASC Nano 6, 9951 (2012).
R. Larciprete, S. Ulstrup, P. Lacovig, M. Dalmiglio, M. Bianchi, F. Mazzola, L. Hornekær, F. Orlando, A. Baraldi, P. Hofmann, and S. Lizzit, ASC Nano 6, 9551 (2012).
E. V. Rut’kov and N. R. Gall, in Physics and Applications of Graphene—Experiments, Ed. by S. Mikhailov (InTech, Rijeka, Croatia, 2011).
N. R. Gall, E. V. Rut’kov, and A. Ya. Tontegode, Int. J. Mod. Phys. 11, 1865 (1997).
A. Ya. Tontegode, Prog. Surf. Sci. 38, 201 (1991).
E. Ya. Sandberg and N. I. Ionov, Surface Ionization (Nauka, Moscow, 1969; Israel Program for Sci. Transl., Jerusalem, 1971).
E. V. Rut’kov, E. Yu. Afanas’eva, and N. R. Gall, Semiconductors 54 (6) (2020, in press).
E. V. Rut’kov and N. R. Gall, JETP Lett. 110, 683 (2019).
N. R. Gall, E. V. Rut’kov, A. Ya. Tontegode, and Yu. N. Tsarev, JETP Lett. 71, 457 (2000).
N. R. Gall and E. V. Rut’kov, JETP Lett. 88, 268 (2008).
Author information
Authors and Affiliations
Corresponding author
Additional information
Russian Text © The Author(s), 2020, published in Pis’ma v Zhurnal Eksperimental’noi i Teoreticheskoi Fiziki, 2020, Vol. 111, No. 8, pp. 520–523.
Rights and permissions
About this article
Cite this article
Rut’kov, E.V., Afanas’eva, E.Y. & Gall, N.R. Differences in the Equilibrium and Critical Degrees of Coating in a Phase Transition in a Carbon Layer on a Metal at the Formation of Graphene. Jetp Lett. 111, 452–455 (2020). https://doi.org/10.1134/S0021364020080093
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0021364020080093