Abstract
A carbon template has been silicided with gaseous SiO at 1350°C in vacuum using a mixture of silicon and silicon dioxide powders as a SiO source and pyrolyzed birch wood as a carbon template. The results demonstrate the feasibility of producing biomorphic SiC whose microstructure replicates the structure of the carbon template. The material thus obtained has a porosity of about 80% and an axial compressive strength of 35 MPa.
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De Arellano-Lopez, A.R., Martinez-Fernandez, J., Gonzalez, P., et al., Biomorphic SiC: A new engineering — ceramic material, Int. J. Appl. Ceram. Technol., 2004, vol. 1, no. 1, pp. 56–67.
Yan, Z., Liu, J., Zhang, J., et al., Biomorphic silicon/silicon carbide ceramics from birch powder, Ceram. Int., 2011, vol. 37, pp. 725–730.
Maity, A., Kalita, D., Kayal, T.K., et al., Synthesis of SiC ceramics from processed cellulosic bio-precursor, Ceram. Int., 2010, vol. 36, pp. 323–331.
Bautista, M.A., Cancapa, J.Q., Martinez-Fernandez, J., et al., Microstructural and mechanical evaluation of porous biomorphic silicon carbide for high temperature filtering applications, J. Eur. Ceram. Soc., 2011, vol. 31, pp. 1325–1332.
Calderon, N.R., Martinez-Escandell, M., Narciso, J., and Rodriguez-Reinoso, F., Manufacture of biomorphic SiC components with homogeneous properties from sawdust by reactive infiltration with liquid silicon, J. Am. Ceram. Soc., 2010, vol. 93, no. 4, pp. 1003–1009.
Locs, J., Berzina-Cimdina, L., Zhurinsh, A., and Loca, D., Effect of processing on the microstructure and crystalline phase composition of wood derived porous SiC ceramics, J. Eur. Ceram. Soc., 2011, vol. 31, pp. 183–188.
Vyshnyakova, K., Yushin, G., Pereselentseva, L., and Gogotsi, Y., Formation of porous SiC ceramics by pyrolysis of wood impregnated with silica, Int. J. Appl. Ceram. Technol., 2006, vol. 3, no. 6, pp. 485–490.
Ghosh, S.S., Mandal, P.K., and Majumdar, R., Replication of jute stem for porous cellular ceramics/composites in the SiO2-SiC-C system, Ceram. Int., 2010, vol. 36, pp. 2063–2071.
Gong, W., Gao, P., and Wang, W., Characterization and oxidation properties of biomorphic porous carbon with SiC gradient coating prepared by PIP method, Ceram. Int., 2011, vol. 37, pp. 1739–1746.
Kozhevnikov, G.N. and Vodop’yanov, A.G., Nizshie okisly kremniya i alyuminiya v elektrometallurgii (Lower Silicon and Aluminum Oxides in Electrometallurgy), Moscow: Nauka, 1977.
Istomina, E.I., Istomin, P.V., and Nadutkin, A.V., Siliciding of titanium carbides with gaseous SiO, Russ. J. Inorg. Chem., 2012, vol. 57, no. 8, pp. 1058–1063.
Istomina, E.I., Istomin, P.V., and Nadutkin, A.V., Effect of titanium carbide stoichiometry on Ti3SiC2 formation in the TiC-SiO system, Izv. Komi Nauchn. Tsentra Ural. Otd. Ross. Akad. Nauk, 2011, no. 4 (8), pp. 24–28.
Kazenas, E.K. and Tsvetkov, Yu.V., Isparenie oksidov (Vaporization of Oxides), Moscow: Nauka, 1997.
Kraus, W. and Nolze, G., Powder Cell—a program for the representation and manipulation of crystal structures and calculation of the X-ray powder patterns, J. Appl. Crystallogr., 1996, vol. 29, p. 301.
Khaenko, B.V., Prilutskii, E.P., Mikhailik, A.A., et al., Phase state and crystal structure of products obtained by reaction of SiC with SiO2, Inorg. Mater., 1995, vol. 31, no. 3, pp. 304–309.
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Original Russian Text © E.I. Istomina, P.V. Istomin, A.V. Nadutkin, 2013, published in Neorganicheskie Materialy, 2013, Vol. 49, No. 10, pp. 1060–1064.
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Istomina, E.I., Istomin, P.V. & Nadutkin, A.V. Preparation of biomorphic SiC. Inorg Mater 49, 984–987 (2013). https://doi.org/10.1134/S0020168513090070
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DOI: https://doi.org/10.1134/S0020168513090070