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Nitration of Phenol with Water Activated by Pulsed Hot Plasma Radiation

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Abstract

The nitration of phenol with plasma-activated water (PAW) generated by pulsed radiation of an electric spark discharge has been studied. Long-lived nitrogen-containing active species that accumulate in water during treatment are nitrous acid and the …ONOOH/ONOO− complex, which decomposes into peroxynitrite and peroxynitrous acid. Their concentration in PAW after 10 min of treatment was ~10−3 mol/L. When PAW is mixed with phenol in a 1 : 1 ratio, the identified reaction product is 4-nitrophenol. The yield of nitration through PAW is equal to the nitration yield by the direct action of hot plasma radiation on a phenol solution.

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REFERENCES

  1. Zhou, Renwu, Zhou, Rusen, Wang, P., et al., J. Phys. D: Appl. Phys., 2020, vol. 53, no. 30, p. 303001.

    Article  CAS  Google Scholar 

  2. Balan, G.G., Rosca, I., Ursu, E.-L., et al., Infect. Drug Resist., 2018, vol. 11, p. 727.

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  3. Vlad, I.E., Martin, C., Toth, A.R., et al., Rom. Rep. Phys., 2019, vol. 71.

  4. Mai-Prochnow, A., Zhou, R., Zhang, T., et al., Biofilms Microbiomes, 2021, vol. 7, p. 11.

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  5. Julak, J., Hujacova, A., Scholtz, V., et al., Plasma Phys. Rep., 2018, vol. 44, no. 1, p. 125.

    Article  Google Scholar 

  6. Patel, S.S., Patel, D.B., and Patel, H.D., ChemistrySelect, 2021, vol. 6, p. 1.

    Article  Google Scholar 

  7. Hoggett, G., Moodie, R.B., Penton, J.R., and Schofield, K., Nitration and Aromatic Reactivity, London: Cambridge University Press, 1971.

    Google Scholar 

  8. Uppi, R.M., Lemercier, J-N., Zhang, H., Prior, W.A., et al., Arch. Biochem. Biophys., 1998, vol. 358, no. 1, p. 1.

    Article  Google Scholar 

  9. Bowers, G.N., McComb, R.B., Christensen, R.G., and Schaffer, R., Clin. Chem., 1980, vol. 26, no. 6, p. 724.

    Article  CAS  PubMed  Google Scholar 

  10. Amani, K. and Maleki, F., J. Iran. Chem. Soc., 2007, vol. 4, no. 2, p. 238.

    Article  CAS  Google Scholar 

  11. Pourali, A.R. and Goli, A., J. Chem. Sci., 2011, vol. 123, no. 1, p. 63.

    Article  CAS  Google Scholar 

  12. Patil, M.R., Mohite, P.H., Shisodia, S., and Keri, S., Lett. Org. Chem., 2015, vol. 12, no. 2, p. 129.

    Article  CAS  Google Scholar 

  13. Ivanova, I.P. and Piskarev, I.M., High Energy Chem., 2022, vol. 56, no. 5, p. 339.

    Article  CAS  Google Scholar 

  14. Piskarev, I.M., High Energy Chem., 2016, vol. 50, no. 5, p. 424.

    Article  CAS  Google Scholar 

  15. Piskarev, I.M. and Ivanova, I.P., Plasma Chem. Plasma Process., 2021, vol. 41, no. 1, p. 447.

    Article  CAS  Google Scholar 

  16. Piskarev, I.M. and Ivanova, I.P., Plasma Sources Sci. Technol., 2019, vol. 28, no. 10, p. 085008.

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Skobeltsyn Research Institute of Nuclear Physics, Moscow State University, 119234, Moscow, Russia

    I. M. Piskarev

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  1. I. M. Piskarev
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Correspondence to I. M. Piskarev.

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Translated by S. Zatonsky

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Piskarev, I.M. Nitration of Phenol with Water Activated by Pulsed Hot Plasma Radiation. High Energy Chem 57, 379–383 (2023). https://doi.org/10.1134/S0018143923040112

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  • DOI: https://doi.org/10.1134/S0018143923040112

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