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Radiation telomerization of tetrafluoroethylene in tetrahydrofuran

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Abstract

According to DSC, DTG, and GPC data, H(CF2CF2)nC4H7O telomers with a chain length of n = 1−4 and T b ≈ 170−200°C were formed during the radiolysis of a binary mixture of tetrafluoroethylene + tetrahydrofuran in a molar ratio of (0.37–2)/1 between the reactants at room temperature. IR spectroscopy and quantum-chemical calculations demonstrated that telomerization occurred with chain transfer through the α-hydrogen of the furan ring.

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References

  1. Ameduri, B. and Boutevin, B., Well-Architectured Fluoropolymers: Synthesis, Properties and Applications, Amsterdam: Elsevier, 2004.

    Google Scholar 

  2. Kotov, S., Kostov, G., and Balbolov, E., React. Kinet. Catal. Lettt, 1998, vol. 63, no. 1, p. 107.

    Article  CAS  Google Scholar 

  3. Wlassics, I. and Tortelli, V., J. Fluorine Chem., 2006, vol. 127, no. 2, p. 240.

    Article  CAS  Google Scholar 

  4. Kuzaev, A.I., Kim, I.P., Kiryukhin, D.P., and Bouznik, V.M., Vysokomol. Soedin., Ser. A, 2009, vol. 51, no. 7, p. 1122.

    CAS  Google Scholar 

  5. Perdew, J.P., Burke, K., and Ernzerhof, M., Phys. Rev. Lett., 1996, vol. 77, p. 3685.

    Article  Google Scholar 

  6. Stevens, W.J., Basch, H., and Krauss, M., J. Chem. Phys., 1984, vol. 81, p. 6026.

    Article  Google Scholar 

  7. Laikov, D.N. and Ustynyuk, Yu.A., Izv. Akad. Nauk, Ser. Khim., 2005, p. 804.

  8. Brown, D.E. and Beagley, B., J. Mol. Struct., 1977, vol. 38, p. 167.

    Article  CAS  Google Scholar 

  9. Rayón, V.M. and Sordo, J.A., J. Chem. Phys., 2005, vol. 122, p. 204303.

    Article  Google Scholar 

  10. Kalasinsky, V.F., Anjaria, H.V., and Little, T.S., J. Phys. Chem., 1982, vol. 86, p. 1351.

    Article  CAS  Google Scholar 

  11. Eyster, J.M. and Prohofsky, E.W., Spectrochim. Acta, 1974, vol. 30, p. 2041.

    Article  Google Scholar 

  12. Kim, I.P., Khim. Vys. Energ., 2011, vol. 45, no. 5, p. 399 [High Energy Chem., 2009, vol. 45, no. 5, p. 365].

    Google Scholar 

  13. Shestakov, A.F. and Kim, I.P., Khim. Vys. Energ., 2009, vol. 43, no. 6, p. 555 [High Energy Chem., 2009, vol. 43, no. 6, p. 499].

    Google Scholar 

  14. Kim, I.P. and Shestakov, A.F., Khim. Vys. Energ., 2009, vol. 43, no. 6, p. 516 [High Energy Chem., 2009, vol. 43, no. 6, p. 460].

    Google Scholar 

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Authors and Affiliations

  1. Institute of Problems of Chemical Physics, Russian Academy of Sciences, pr. Akademika Semenova 1, Chernogolovka, Moscow oblast, 142432, Russia

    I. P. Kim, E. O. Perepelitsyna, A. F. Shestakov, Yu. M. Shul’ga & A. A. Kunitsa

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  1. I. P. Kim
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  2. E. O. Perepelitsyna
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  3. A. F. Shestakov
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  4. Yu. M. Shul’ga
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  5. A. A. Kunitsa
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Correspondence to I. P. Kim.

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Original Russian Text © I.P. Kim, E.O. Perepelitsyna, A.F. Shestakov, Yu.M. Shul’ga, A.A. Kunitsa, 2011, published in Khimiya Vysokikh Energii, 2011, Vol. 45, No. 6, pp. 511–516.

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Kim, I.P., Perepelitsyna, E.O., Shestakov, A.F. et al. Radiation telomerization of tetrafluoroethylene in tetrahydrofuran. High Energy Chem 45, 475–480 (2011). https://doi.org/10.1134/S0018143911060117

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  • DOI: https://doi.org/10.1134/S0018143911060117

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