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Chlorination of Sulfonium Derivatives of closo-Decaborate Anion with Carboxyl-Containing Substituents

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Abstract

The reaction of sulfonium closo-decaborate derivatives containing carboxyl groups with sulfuryl chloride SO2Cl2 as a halogenating agent was studied. The reaction gave fully halogenated derivatives of the closo-decaborate anion, (n-Bu4N)[2-B10Cl9SR2] (R = –CH2COOEt, –CH2COOH), which was confirmed by 11B, 1H, and 13C NMR and IR spectral data. The structure of the [2-B10Cl9S(CH2COOEt)2]– anion was established using single crystal X-ray diffraction.

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Funding

The study was supported by the Russian Foundation for Basic Research (project no. 20-33-90118). The study was supported by the state assignment for the Kurnakov Institute of General and Inorganic Chemistry, RAS. X-ray diffraction, IR, and NMR measurements were carried out using the research equipment supported by the state assignment for IGIC RAS.

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia

    A. V. Golubev, A. S. Kubasov, A. Yu. Bykov,  K. Yu. Zhizhin &  N. T. Kuznetsov

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  1. A. V. Golubev
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  2. A. S. Kubasov
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  3. A. Yu. Bykov
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  4. K. Yu. Zhizhin
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  5. N. T. Kuznetsov
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Corresponding author

Correspondence to A. V. Golubev.

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The authors declare that they have no conflicts of interest.

Additional information

Translated by Z. Svitanko

This study was submitted to the virtual issue “Young Scientists of the RAS.”

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Golubev, A.V., Kubasov, A.S., Bykov, A.Y. et al. Chlorination of Sulfonium Derivatives of closo-Decaborate Anion with Carboxyl-Containing Substituents. Dokl Chem 500, 205–208 (2021). https://doi.org/10.1134/S0012500821100025

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