Abstract
The anodic oxidation of a titanium metal electrode in two ionic liquids was studied of amorphous titania nanostructures were obtained. The nanostructures are formed only in the case where a hydrophilic ionic liquid (1-butyl-3-methylimidazolium chloride) with addition of some water is used as the electrolyte. The role of water is to provide a sort of construction material (source of oxygen) for titania nanostructures. In the hydrophobic ionic liquid (1-butyl-3-methylimidazolium), the thickness of the anodic oxide increases and no nanostructures are formed.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
Fukuzumi, S. and Yamada, Y., ChemSusChem, 2013, vol. 6, no. 10, pp. 1834–1847. doi 10.1002/cssc.201300361
Kleijn, S.E.F., Lai, S.C.S., Koper, M.T.M., and Unwin, P.R., Angew. Chem., Int. Ed., 2014, vol. 53, no. 14, pp. 3558–3586. doi 10.1002/anie.201306828
Choi, H., Kim, Y.J., Varma, R.S., and Dionysiou, D.D., Chem. Mater., 2006, vol. 18, no. 22, pp. 5377–5384. doi 10.1021/cm0615626
Ding, K., Miao, Z., Liu, Z., Zhang, Z., Han, B., An, G., Miao, S., and Xie, Y., J. Am.Chem. Soc., 2007, vol. 129, no. 20, pp. 6362–6363. doi 10.1021/ja070809c
Zheng, W., Liu, X., Yan, Z., and Zhu, L., ACS Nano, 2009, vol. 3, no. 1, pp. 115–122. doi 10.1021/nn800713w
Root, N.V., Kultin, D.Yu., Kustov, L.M., Kudryavtsev, I.K., and Lebedeva, O.K., Russ. J. Phys. Chem. A, 2017, vol. 91, no. 2, pp. 213–216. doi 10.7868/S0044453717020248
Lebedeva, O., Jungurova, G., Kultin, D., Kustov, L., Zakharov, A., Kalmikov, K., Chernikova, E., and Krasovskiy, V., Green Chem., 2011, vol. 13, no. 4, pp. 1004–1008. doi 10.1039/C0GC00880J
Lebedeva, O.K., Kul’tin, D.Yu., Root, N.V., Kustov, L.M., Dzhungurova, G.L., Kalmykov, K.B., and Dunaev, S.F., RF Patent 2592892 C1, 2016. http://www1.fips.ru/fips_servl/fips_servlet? DB=RUPAT&DocNumber=2592892&Type-File=html
Wu, H.Q. and Hebert, K.R., Electrochim. Acta, 2002, vol. 47, pp. 1373–1383. doi 10.1016/S0013-4686(01)00862-3
Lebedeva, O., Kultin, D., Kudryavtsev, I., Root, N., and Kustov, L., Electrochem. Commun., 2017, vol. 75, pp. 78–81. doi 10.1016/j.elecom.2017.01.005
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © O.K. Lebedeva, D.Yu. Kultin, N.V. Root, L.M. Kustov, S.F. Dunaev, V.B. Kazansky, 2018, published in Doklady Akademii Nauk, 2018, Vol. 479, No. 4, pp. 399–403.
Rights and permissions
About this article
Cite this article
Lebedeva, O.K., Kultin, D.Y., Root, N.V. et al. Synthesis of Nanotitania on the Surface of Titanium Metal in Ionic Liquids: Role of Water Additions. Dokl Chem 479, 41–44 (2018). https://doi.org/10.1134/S001250081804002X
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S001250081804002X