Abstract
An indirect electrochemical method for thiolation of cycloalkanes C5–C7 has been suggested. The method is based on a new approach to activation of hydrogen sulfide by redox mediators.
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Moiseev, I.I., Russ. Chem. Rev., 2013, vol. 82, no. 7, pp. 616–623.
Francke, R. and Little, R.D., Chem. Soc. Rev., 2014, vol. 43, pp. 2492–2521.
Budnikova, Yu.G. and Budnikov, G.K., Zh. Org. Khim., 1995, vol. 65, no. 9, pp. 1517–1535.
Berberova, N.T. and Shinkar’, E.V., Izv. Akad. Nauk, Ser. Khim., 2000, no. 7, pp. 1182–1188.
Berberova, N.T., Shinkar’, E.V., Smolyaninov, I.V., and Okhlobystin, A.O., Vovlechenie serovodoroda, tiolov i polisul’fanov v sintez organicheskikh soedinenii sery (Involvement of Hydrogen Sulfide, Thiols, and Polysulfanes in the Synthesis of Organic Sulfur Compounds), Rostov-on-Don: Izd. SSC RAN, 2009.
Okhlobystin, A.O., Okhlobystina, A.V., Shinkar’, E.V., Berberova, N.T., and Eremenko, I.L., Dokl. Chem., 2010, vol. 435, part 1, pp. 302–306.
Okhlobystin, A.O., Smolyaninov, I.V., Okhlobystina, A.V., Berberova, N.T., Koldaeva, Yu.Yu., and Abdulaeva, V.F., Russ. J. Coord. Chem., 2013, vol. 39, no. 1, pp. 33–36.
Al’fonsov, V.A., Belen’kii, L.I., Vlasova, N.N., et al., Poluchenie i svoistva organicheskikh soedinenii sery (Synthesis and Properties of Sulfur Compounds), Moscow: Khimiya, 1998.
Berberova, N.T., Shinkar’, E.V., Smolyaninov, I.V., and Abdulaeva, V.F., Russ. J. Gen. Chem., 2015, vol. 85, no. 4, pp. 998–1000.
Berberova, N.T., Khokhlov, V.A., Shinkar’, E.V., Manyashin, A.O., and Alekhina, Yu.Yu., Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol., Ser. Khim., 2008, vol. 51, no. 6, pp. 45–48.
Berberova, N.T., Shinkar’, E.V., Smolyaninov, I.V., Okhlobystin, A.O., Koldaeva, Yu.Yu., Vasil’eva, E.A., and Petrova, N.V., RF Patent no. 2498938, Byull. Izobret., 2013.
Izmest’ev, E.S., Lezina, O.M., Grebenkina, O.N., Patov, S.A., Rubtsova, S.A., and Kuchin, A.V., Izv. Akad. Nauk, Ser. Khim., 2014, no. 9, p. 2067.
Guillanton, G., Tho Do, Q., and Elothmani, D., J. Electrochem. Soc., 1996, vol. 143, no. 10, pp. 223–225.
Okhubo, K., Fujimoto, A., and Fukuzumi, S., Chem. Commun., 2011, vol. 47, pp. 8515–8517.
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Original Russian Text © N.T. Berberova, E.V. Shinkar’, I.V. Smolyaninov, K.P. Pashchenko, 2015, published in Doklady Akademii Nauk, 2015, Vol. 465, No. 6, pp. 683–686.
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Berberova, N.T., Shinkar’, E.V., Smolyaninov, I.V. et al. Redox mediators of hydrogen sulfide oxidation in reactions with cycloalkanes. Dokl Chem 465, 295–298 (2015). https://doi.org/10.1134/S0012500815120058
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DOI: https://doi.org/10.1134/S0012500815120058