Skip to main content
Log in

Seasonal and Inter Annual Variations between Concentrations and Fluxes of Dissolved and Particulate Organic Carbon, Iron and Manganese from the Northern Dvina River to the White Sea

  • MARINE CHEMISTRY
  • Published:
Oceanology Aims and scope

Abstract

The paper presents new data on concentrations and fluxes of organic carbon, iron, and manganese in waters of the mouth area of the Northern Dvina River. The work was conducted within the project “Northern Dvina River Marginal Filter Observatory” from May 2015 to May 2019 with monthly collection of water samples. Systematic determinations of the concentrations of the main carrier elements of many trace elements in dissolved and particulate forms were used to establish the average weighted of Corg, Fe, and Mn concentrations. The results of 4 years of systematic investigations established the main regularities of seasonal variations of dissolved and particulate forms of element concentrations and the relationships between. Significant variations were observed not only between concentrations but also between fluxes of elements in both forms. However, more than half the annual fluxes of all elements in all years studied was transported to the sea in the spring flood period. The results also demonstrated significant variations between element concentrations and their fluxes in different years. This is unsurprising, since even during the 4 years of investigations, the difference between water runoff and SPM fluxes in different years was up to, respectively, 1.4 and 2.6 times.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.
Fig. 5.
Fig. 6.
Fig. 7.

Similar content being viewed by others

REFERENCES

  1. V. E. Artem’ev, Geochemistry of Organic Matter in the River–Sea System (Nauka, Moscow, 1993) [in Russian].

    Google Scholar 

  2. V. V. Gordeev, River Runoff in Ocean and its Main Geochemical Features (Nauka, Moscow, 1983) [in Russian].

    Google Scholar 

  3. V. V. Gordeev, A. S. Filippov, M. V. Kravchishina, et al., “Specific geochemistry of river run-off to the White Sea,” in The White Sea System, Vol. 2: Water Column and Interacting Atmosphere, Cryosphere, River Run-Off, and Biosphere (Nauchnyi Mir, Moscow, 2012), pp. 225–308.

  4. V. V. Gordeev and V. P. Shevchenko, “Forms of some metals in the suspended sediments of the Northern Dvina River and their seasonal variations,” Oceanology (Engl. Transl.) 52, 261–270 (2012).

  5. V. V. Ivanov and V. A. Bryzgalo, “Hydrological-hydrochemical regime of the White Sea watershed,” in The White Sea and Its Watershed Affected by Climate and Anthropogenic Factors, Ed. by N. N. Filatov and A. Yu. Terzhevik (Karelian Scientific Center, Russian Academy of Sciences, Petrozavodsk, 2007), pp. 119–145.

    Google Scholar 

  6. V. N. Korotaev, Geomorphology of River Deltas (Moscow State Univ., Moscow, 1991) [in Russian].

    Google Scholar 

  7. A. I. Kochetkova, A. N. Novigatskii, V. V. Gordeev, et al., “Features of seasonal distribution of a suspended matter and organic carbon according to marginal filter of the Severnaya Dvina River Observatory,” Okeanol. Issled. 46 (2), 96–111 (2018).

    Google Scholar 

  8. M. D. Kravchishina, V. P. Shevchenko, A. S. Filippov, et al., “Composition of the suspended particulate matter at the Severnaya Dvina River mouth (White Sea) during the spring flood period,” Oceanology (Engl. Transl.) 50, 365–385 (2010).

  9. A. V. Leshchev, G. D. Khomenko, V. B. Korobov, et al., “Fieldworks in the Northern Dvina estuary in March 2014,” Oceanology (Engl. Transl.) 55, 315–317 (2015).

  10. A. V. Leshchev, I. V. Miskevich, V. B. Korobov, et al., “Spatial features of tidal variability of the hydrological and hydrochemical characteristics in the Northern Dvina River mouth area during the winter low-water period,” Oceanology (Engl. Transl.) 57, 270–277 (2017).

  11. A. P. Lisitsyn, V. P. Shevchenko, V. I. Burenkov, et al., “Suspended matter and hydrooptics of the White Sea: new pattern of quantitative distribution and granulometry,” in Relevant Problems of Oceanology, Ed. by N. P. Laverov (Nauka, Moscow, 2003), pp. 556–607.

    Google Scholar 

  12. V. N. Mikhailov, Estuaries of Russian Rivers and Adjacent Countries: Past, Present, Future (GEOS, Moscow, 1997) [in Russian].

    Google Scholar 

  13. N. P. Morozov, G. N. Baturin, V. V. Gordeev, and E. G. Gurvich, “Composition of suspended matter and sediments in estuarine areas of the Severnaya Dvina, Mezen’, Pechora, Ob’ rivers,” Gidrokhim. Mater. 60, 60–73 (1974).

    Google Scholar 

  14. A. M. Nikanorov, L. P. Sokolova, O. S. Reshetnyak, et al., “Anthropogenic load on the estuarine area of the Northern Dvina River,” Russ. Meteorol. Hydrol. 35, 281–288 (2010).

    Article  Google Scholar 

  15. E. A. Romankevich, G. A. Korneeva, V. P. Shevchenko, et al., “Suspended organic matter in the Barents Sea,” Oceanology (Engl. Transl.) 40, 192–200 (2000).

  16. E. A. Romankevich and A. A. Vetrov, Carbon Cycle in Arctic Seas of Russia (Nauka, Moscow, 2001) [in Russian].

    Google Scholar 

  17. V. S. Savenko, O. S. Pokrovskii, B. Dupre, and G. N. Baturin, “Chemical composition of suspended matter of the big rivers Russia and adjacent countries,” Dokl. Earth Sci. 398, 938–942 (2004).

    Google Scholar 

  18. V. P. Shevchenko, O. S. Pokrovsky, A. S. Filippov, et al., “On the elemental composition of suspended matter of the Severnaya Dvina River (White Sea region),” Dokl. Earth Sci. 430, 228–234 (2010).

    Article  Google Scholar 

  19. N. V. Shorina, V. P. Shevchenko, T. Ya. Vorob’eva, et al., “distribution of iron forms in estuarine area of the Severnaya Dvina River and Dvina Bay of the White Sea,” Voda: Khim. Ekol., No. 10, 32–37 (2014).

  20. V. E. Artemiev and E. A. Romankevich, “Seasonal variations in the transport of organic matter in the North Dvina estuary,” in Transport of Carbon and Minerals in Major World Rivers and Lakes, SCOPE/UNEP Sonderband No. 66, Ed. by E. Degens, S. Kempe, and A. S. Naidu (Hamburg, 1988), pp. 177–184.

  21. N. N. Bobrovitskaya, A. V. Kokorev, and N. A. Lemeshko, “Regional patterns in recent trends in sediment yields of Eurasian and Siberian rivers,” Global Planet. Change 39, 127–146 (2003).

    Article  Google Scholar 

  22. A. V. Chupakov, O. S. Pokrovsky, O. Y. Moreva, et al., “High resolution multi-annual riverine fluxes of organic carbon, nutrients and trace elements from the largest European Arctic river, Severnaya Dvina,” Chem. Geol. 538, 119491 (2020).

    Article  Google Scholar 

  23. Yu. A. Fedorov, A. E. Ovsepyan, and V. B. Korobov, “Peculiarities of mercury distribution, migration and transformation in the estuarine area of the Northern Dvina River, Russian,” Meteorol. Hydrol. 35 (4), 289–294 (2010).

    Article  Google Scholar 

  24. V. V. Gordeev and M. D. Kravchishina, “River flux of dissolved organic carbon (DOC) and particulate organic carbon (POC) to the Arctic Ocean: what are the consequences of the global changes?” in Influence of Climate Change on the Changing Arctic and Sub-Arctic Conditions, Ed. by J. C. J. Nihoul and A. G. Kostianoy (Springer-Verlag, Dordrecht, 2009), pp. 139–154.

    Google Scholar 

  25. V. V. Gordeev, O. S. Pokrovsky, and V. P. Shevchenko, “The geochemical features of the river discharge to the White Sea,” in Biogeochemistry of the Atmosphere, Ice and Water of the White Sea: The White Sea Environment, Ed. by A. P. Lisitsyn and V. V. Gordeev (Springer-Verlag, Cham, 2018), Part 1, pp. 47–81.

  26. J. E. Hobbie, B. J. Peterson, N. Better, et al., “Impact of global change on the biogeochemistry and ecology of an Arctic freshwater system,” Polar Res. 18 (2), 207–214 (1999).

    Article  Google Scholar 

  27. R. M. Holmes, B. J. Peterson, V. V. Gordeev, et al., “Flux of nutrients from Russian rivers to the Arctic Ocean: can we establish a baseline against which to judge future changes?” Water Res. 36 (8), 2309–2320 (2000).

    Article  Google Scholar 

  28. R. M. Holmes, J. W. McClelland, B. J. Peterson, et al., “Seasonal and annual fluxes of nutrients and organic matter from large rivers to the Arctic Ocean and surrounding seas,” Estuarine Coasts 35, 369–382 (2012).

    Article  Google Scholar 

  29. S. E. Johnston, N. Shorina, K. Bulygina, et al., “Flux and seasonality of dissolved organic matter from the Northern Dvina (Severnaya Dvina) River, Russia,” J. Geophys. Res.: Biogeosci. 123, 1041–1056 (2018).

    Article  Google Scholar 

  30. H. Kohler, B. Meon, V. Gordeev, et al., “Dissolved organic matter (DOM) in the rivers Ob’ and Yenisey and in the adjacent Kara Sea,” in Siberian River Run-off in the Kara Sea: Characterization, Quantification, Variability and Environmental Significance, Ed. by R. Stein, (Elsevier, New York, 2003), pp. 281–308.

    Google Scholar 

  31. I. V. Krickov, A. G. Lim, R. M. Manasypov, et al., “Major and trace elements in suspended matter of western Siberian rivers: first assessment across permafrost zones and landscape parameters of watersheds,” Geochim. Gosmochim. Acta 269, 429–450 (2020).

    Article  Google Scholar 

  32. R. J. Lara, V. Rachold, G. Kattner, et al., “Dissolved organic matter and nutrients in the Lena river, Siberian Arctic: characteristics and distribution,” Mar. Chem. 59, 301–309 (1998).

    Article  Google Scholar 

  33. J. M. Lobbes, H. P. Fitznar, and G. Kattner, “Biogeochemical characteristics of dissolved and particulate organic matter in Russian rivers entering the Arctic Ocean,” Geochim., Cosmochin. Acta 64, 2973–2983 (2000).

    Article  Google Scholar 

  34. R. W. Macdonald, S. M. Solomon, R. E. Cranston, et al., “Sediment and organic carbon budget for the Canadian Beaufort shelf,” Mar. Geol. 144, 255–273 (1998).

    Article  Google Scholar 

  35. J. W. McClelland, R. M. Holmes, P. Raymond, et al., “Particulate organic carbon and nitrogen expert from major Arctic rivers,” Global Biogeochem. Cycles 30, 629–643 (2016).

    Article  Google Scholar 

  36. B. J. Peterson, R. M. Holmes, J. W. McClelland, et al., “Increasing river discharge to the Arctic Ocean,” Science 298, 2171–2173 (2002).

    Article  Google Scholar 

  37. O. S. Pokrovsky, J. Viers, L. S. Shirokova, et al., “Dissolved, suspended and colloidal fluxes of organic carbon, major and trace elements in the Severnaya Dvina River and its tributary,” Chem. Geol. 273, 136–149 (2010).

    Article  Google Scholar 

  38. V. A. Rachold, H. Eicken, V. V. Gordeev, et al., “Modern terrigenous organic carbon input to the Arctic Ocean,” in The Organic Carbon Cycle in the Arctic Ocean, Ed. by R. Stein and R. W. Macdonald (Springer-Verlag, Berlin, 2004), pp. 33–55.

    Google Scholar 

  39. I. P. Semiletov, I. I. Pipko, N. E. Shakhova, et al., “Carbon transport by the Lena River from its headwaters to the Arctic Ocean, with emphasis on fluvial input of terrestrial particulate organic carbon vs. carbon transport by coastal erosion,” Biogeosciences 8, 2407–2426 (2011).

    Article  Google Scholar 

  40. L. S. Shirokova, A. A. Chuparova, A. V. Chupakov, and O. S. Pokrovsky, “Transformation of dissolved organic matter and related trace element in the mouth zone of the largest European Arctic river: experimental modeling,” Inland Waters 7 (3), 272–282 (2017).

    Article  Google Scholar 

Download references

ACKNOWLEDGMENTS

The authors are grateful A.P. Lisitsyn for valuable advice and support and to V.B. Korobov for help in organizing the sampling.

Funding

The material was obtained under the state task of IO RAS (topic no. 0149-2019-0007). Processing and interpretation of material was supported by the Russian Science Foundation (grant no. 19-17-00234).

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to V. V. Gordeev.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Gordeev, V.V., Kochenkova, A.I., Lokhov, A.S. et al. Seasonal and Inter Annual Variations between Concentrations and Fluxes of Dissolved and Particulate Organic Carbon, Iron and Manganese from the Northern Dvina River to the White Sea. Oceanology 61, 34–47 (2021). https://doi.org/10.1134/S0001437021010069

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0001437021010069

Keywords:

Navigation