Abstract
The structure of the proton sublattice of ice at an ice-metal interface is analyzed by solving the Ginzburg-Landau equation for an order parameter describing the proton ordering under an appropriate boundary condition [1, 2]. When the interaction between protons and the substrate is weak, the ice rules that govern proton order are weaker at the interface as compared to bulk ice, but to a lesser extent than at the free ice surface. In the case of strong proton-substrate interaction (clean interface and/or high conductivity of the substrate), the ice rules are stronger at the interface as compared to bulk ice, which corresponds to a more ordered proton sublattice. The latter case corresponds to a lower concentration of defects in the proton sublattice, which determine important properties of ice, such as adhesion, electrical conductivity, plasticity, and electric field distribution near the interface. A qualitative correlation is described between electrical properties of the substrate and mechanical properties of the interface, including adhesion and friction.
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References
I. A. Ryzhkin and V. F. Petrenko, Phys. Rev. B 62, 11280 (2000).
I. A. Ryzhkin and V. F. Petrenko, Phys. Rev. B 65, 12205 (2002).
V. F. Petrenko and R. W. Whitworth, Physics of Ice (Oxford Univ. Press, Oxford, 1999).
M. Faraday, Philos. Mag. 17, 162 (1859).
J. Thomson, Proc. R. Soc. London, Ser. A 11, 198 (1861).
I. Golecki and C. Jaccard, Phys. Lett. A 63A, 374 (1977).
A. Kouchi, Y. Furukawa, and T. Kuroda, J. Phys. C1 48, 675 (1987).
V. I. Kvlividze, V. F. Kiselev, and L. A. Ushakova, Dokl. Akad. Nauk SSSR 191, 1088 (1970).
Y. Mizuno and N. Hanafuza, J. Phys. C1 48, 511 (1987).
N. Maeno and H. Nishimura, J. Glaciol. 21, 193 (1978).
N. Maeno, in Physics and Chemistry of Ice, Ed. by E. Whalley, S. J. Jones, and L. W. Gold (Royal Society of Canada, Ottawa, 1973), p. 140.
M. A. Maidique, A. von Hippel, and W. B. Westphal, J. Chem. Phys. 54, 150 (1971).
V. F. Petrenko and I. A. Ryzhkin, J. Phys. Chem. B 101, 6285 (1997).
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Translated from Zhurnal Éksperimental’no\(\overset{\lower0.5em\hbox{$\smash{\scriptscriptstyle\smile}$}}{l} \) i Teoretichesko\(\overset{\lower0.5em\hbox{$\smash{\scriptscriptstyle\smile}$}}{l} \) Fiziki, Vol. 128, No. 2, 2005, pp. 364–369.
Original Russian Text Copyright © 2005 by Ryzhkin, Petrenko.
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Ryzhkin, I.A., Petrenko, V.F. Proton ordering in ice at an ice-metal interface. J. Exp. Theor. Phys. 101, 317–321 (2005). https://doi.org/10.1134/1.2047797
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DOI: https://doi.org/10.1134/1.2047797