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Disorder-order phase transformations and electrical resistivity of nonstoichiometric titanium carbide

  • Lattice Dynamics. Phase Transitions
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Abstract

Phase transformations of the disorder-order type in the homogeneity region of nonstoichiometric titanium carbide TiCy (0.5<y<1.0) have been studied. It has been established that, depending on the actual composition of TiCy, there may form in it for T<980–1000 K a cubic or a trigonal ordered Ti2C phase (space groups Fd3m and \(R\bar 3m\), respectively) and a rhombic ordered Ti3C2 phase (space group C2221). The effect of ordering on the electrical resistivity of the nonstoichiometric carbide TiCy was studied, and the temperatures of the reversible disorder-order equilibrium transitions determined. The ordering in titanium carbide is shown to be a first-order phase transition.

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Authors and Affiliations

  1. Institute for Solid-State Chemistry, Ural Branch of the Russian Academy of Sciences, 620219, Ekaterinburg, Russia

    V. N. Lipatnikov, L. V. Zueva & A. I. Gusev

  2. Institut für Experimentalphysik, Technische Universität Wien, A-1040, Wien, Österreich, Austria

    A. Kottar

Authors
  1. V. N. Lipatnikov
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  2. L. V. Zueva
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  3. A. I. Gusev
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  4. A. Kottar
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Fiz. Tverd. Tela (St. Petersburg) 40, 1332–1340 (July 1998)

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Lipatnikov, V.N., Zueva, L.V., Gusev, A.I. et al. Disorder-order phase transformations and electrical resistivity of nonstoichiometric titanium carbide. Phys. Solid State 40, 1211–1218 (1998). https://doi.org/10.1134/1.1130523

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  • DOI: https://doi.org/10.1134/1.1130523

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