Abstract
In this study, a high-power ultrasonicator (600 W) is employed to examine dye degradation and phenol decomposition efficiencies in the presence of catalysts such as K-OMS-2, TiO2, K-OL-1 doped TiO2 and K-OMS-2 doped TiO2. Methylene blue and phenol are chosen as the model pollutants to test the catalytic activity. Effects of ultrasonic power level or ultrasonic intensity, amount of catalysts used and ultrasonic irradiation time for catalytic degradation and removal of phenol were studied. No d-spacing peak shift was observed in intense XRD peaks of K-OMS-2- and K-OL-1-doped TiO2 materials when compared with commercial TiO2. Scanning and transmission electron micrographs (SEM and TEM) show aggregated particle morphology with spherical and rectangular particles for 5 wt % K-OMS-2/TiO2. Methylene blue dye degradation efficiency in the presence of catalytic ultrasonication follows the order like TiO2 > 5 wt % K-OMS-2/TiO2 > 5 wt % K-OL-1/TiO2. The K-OMS-2- and 5 wt % K-OMS-2-doped TiO2 catalyst showed the best and most promising efficiency for phenol removal in ultrasonication process. K-OMS-2 shows the best phenol removal efficiency of 58% within a short duration (30 min) of catalytic ultrasonic-assisted reaction.
Similar content being viewed by others
References
Destaillats, H., Hung, H.M., and Hoffmann, M.R., Environ. Sci. Technol., 2000, vol. 34, p. 311.
Nagata, Y., Nakagawa, M., Okuno, H., Mizukoshi, Y., Yim, B., and Maeda, Y., Ultrason. Sonochem., 2000, vol. 7, p. 115.
Stavarache, C., Yim, B., Vinatoru, M., and Maeda, Y., Ultrason. Sonochem., 2002, vol. 9, p. 291.
Suslick, K.S., in Ultrasound: Its Chemical, Physical and Biological Effects, Suslick, K.S., Ed., New York: VCH, 1988.
Suslick, K.S., Science, 1990, vol. 247, p. 1439.
Suslick, K.S., Hammerton, D.A., and Cline, R.E., J. Am. Chem. Soc., 1986, vol. 108, p. 5641.
Shutilov, V.A., Fundamental Physics of Ultrasound, New York: Gordon & Breach, 1988.
Li, M., L J.T.I, Sun H.W, Ultroson. Sonochem., 2008, vol. 15, p. 37.
Suslick, K.S. and Price, G.J., Annu. Rev. Mater. Sci., 1999, vol. 29, p. 295.
Dvoranová, D., Brezová, V., Mazúra, M., and Malati, M.A., Appl. Catal., B, 2002, vol. 37, p. 91.
Arroyo, R., Cordoba, G., Padilla, J., and Lara, V.H., Mater. Lett., 2002, vol. 54, p. 397.
Boreskov, G.K., in Catalysis Science and Technology, Anderson, J.R. and Boudart, M., Eds., Berlin: Springer, 1982, vol. 3.
Luo, J., Zhang, Q., Huang, A., and Suib, S.L., Microporous Mesoporous Mater., 2000, vols. 35–36, p. 209.
Ramesh, K., Chen, L., Chen, F., Liu, Y., Wang, Z., and Han, Y.F., Catal. Today, 2008, vol. 131, p. 477.
Kapteijn, F., Singoredjo, L., van Driel, M., Andreini, A., Moulijn, J.A., Ramis, G., and Busca, G., J. Catal., 1994, vol. 150, p. 105.
Jothiramalingam, R., Viswanathan, B., and Varadarajan, T.K., Mater. Chem. Phys., 2006, vol. 100, p. 257.
Yin, Y.G., Xu, W.Q., DeGuzman, R., Suib, S.L., and O’Young, C.L., Inorg. Chem., 1994, vol. 33, p. 4384.
Post, J.E. and Veblen, D.R., Am. Mineral., 1990, vol. 75, p. 477.
Jothiramalingam, R. and Wang, M.K., J. Hazard. Mater., 2007, vol. 147, p. 562.
Carvalho, C., Fernandes, A., Lopes, A., Pinheiro, H., and Goncalves, I., Chemosphere, 2007, vol. 67, p. 1316.
Dincer, A.R., Gunes, Y., and Karakaya, N., J. Hazard. Mater., 2007, vol. 141, p. 529.
Jothiramalingam, R., Viswanathan, B., and Varadarajan, T.K., Catal. Commun., 2005, vol. 6, p. 41.
Gallardo-Amores, J.M., Armaroli, T., Ramis, G., Finocchio, E., and Busca, G., Appl. Catal., B, 1999, vol. 22, p. 249.
Wang, J., Sun, W., Zhang, Z., Xing, Z., Xu, R., Li, R., Li, Y., and Zhang, X., Ultroson. Sonochem., 2008, vol. 15, p. 301.
Lachheb, H., Puzenat, E., Houas, A., Ksibi, M., Elaloui, E., Guillard, C., and Herrmann, J.M., Appl. Catal., B, 2002, vol. 39, p. 75.
Author information
Authors and Affiliations
Corresponding author
Additional information
The article is published in the original.
Rights and permissions
About this article
Cite this article
Jothiramalingam, R., Tsao, T.M. & Wang, M.K. High-power ultrasonic-assisted phenol and dye degradation on porous manganese oxide doped titanium dioxide catalysts. Kinet Catal 50, 741–747 (2009). https://doi.org/10.1134/S0023158409050164
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0023158409050164