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The Mechanism of Chemiluminescence in the Thermal Decomposition of 2,2'-Azodiisobutyronitrile in a Liquid Oxygen-Containing Medium

  • KINETICS AND MECHANISM OF CHEMICAL REACTIONS, CATALYSIS
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Abstract

A mathematical computer model of the detailed mechanism of the chemiluminescent process is developed based on the kinetic data on the nonstationary chemiluminescence accompanying the thermal decomposition of 2,2'-azodiisobutyronitrile in benzene. The model, which includes 16 elementary stages, makes it possible to estimate the rate constants of these reactions and to illustrate the interaction of elementary processes.

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Funding

This study was carried out with the financial support from the Russian Foundation for Basic Research (grant no. 19-53-18019 Bolg_a) and the Bulgarian National Science Fund (grant no. KP-06-Rusiya-28).

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Authors and Affiliations

  1. Emanuel Institute of Biochemical Physics, Russian Academy of Sciences, 117997, Moscow, Russia

    V. V. Naumov, G. F. Fedorova, R. F. Vasil’ev, T. L. Veprintsev, A. V. Trofimov & O. I. Yablonskaya

  2. Institute of Organic Chemistry with the Center of Phytochemistry, Bulgarian Academy of Sciences, 1113, Sofia, Bulgaria

    V. D. Kancheva

  3. Moscow Institute of Physics and Technology, 141701, Dolgoprudny, Moscow oblast, Russia

    A. V. Trofimov

Authors
  1. V. V. Naumov
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  2. G. F. Fedorova
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  3. R. F. Vasil’ev
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  4. V. D. Kancheva
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  5. T. L. Veprintsev
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  6. A. V. Trofimov
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  7. O. I. Yablonskaya
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Corresponding author

Correspondence to A. V. Trofimov.

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Naumov, V.V., Fedorova, G.F., Vasil’ev, R.F. et al. The Mechanism of Chemiluminescence in the Thermal Decomposition of 2,2'-Azodiisobutyronitrile in a Liquid Oxygen-Containing Medium. Russ. J. Phys. Chem. B 15, 63–67 (2021). https://doi.org/10.1134/S1990793121010243

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  • DOI: https://doi.org/10.1134/S1990793121010243

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