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Fe3O4@Si-NH2 Magnetic Reinforcement of Novel Polybutadiene-Based Polyurea

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Abstract

Polybutadiene chemical modification to amine terminated polybutadiene, polyurea and magnetic nanocomposite was settled as the aim of current report. In this regard, amine terminated polybutadiene synthesized through a two consecutive oxidation and amination reactions on polybutadiene. In situ polymerization method was used to prepare polybutadiene-based polyurea. Magnetic nanocomposite synthesized with loading 1-3 weight percent of surface modified magnetite (Fe3O4@Si-NH2) nanoparticle in one-pot reaction of amine terminated polybutadiene with toluene diisocyanate. 1H NMR and FT-IR spectroscopy methods were approved correct synthesize of amine functionalized polybutadiene, polyurea and magnetic nanocomposites. Thermal degradation and characteristics investigated using TGA/DTG and DSC techniques; lower degradation rates with improved thermal stabilities and superior thermal properties with wider thermal service range observed especially in 3 weight percent nanocomposite in comparison with pristine polyurea. In addition to, successful nanocomposite synthesis and fine nanoparticle dispersion confirmed by XRD and SEM methods, remarkable chain orderings of magnetic nanocomposite observed. VSM magnetization characterization proved superparamagnetic characteristics of nanocomposites with direct relationship to the magnetic nanoparticle content.

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ACKNOWLEDGMENTS

The authors would like to thank Imam Khomeini International University (IKIU).

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, Imam Khomeini International University, Qazvin, Iran

    Zahra Rahmatpanah & Mir Mohammad Alavi Nikje

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  1. Zahra Rahmatpanah
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  2. Mir Mohammad Alavi Nikje
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Correspondence to Mir Mohammad Alavi Nikje.

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Rahmatpanah, Z., Nikje, M.M.A. Fe3O4@Si-NH2 Magnetic Reinforcement of Novel Polybutadiene-Based Polyurea. Russ J Appl Chem 95, 1048–1057 (2022). https://doi.org/10.1134/S1070427222070175

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