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Synthesis of New Symmetrical Diamidophosphates Based on meta-Phenylenediamine under Microwave Irradiation

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Abstract

A new series of diphosphorylated amidophosphates was obtained as a result of the reaction of meta-phenylenediamine with dialkyl phosphites in the presence of CCl4 and triethylamine (Atherton–Todd reaction) under microwave irradiation. Structure of all the obtained amidophosphates was established on the basis of 31P, 1H, 13C NMR, IR spectroscopy and mass spectrometry methods, as well as single crystal X-ray diffraction and elemental analysis data.

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Funding

The synthetic part of the work was financially supported by the Kazakh National Women’s Pedagogical University and the Ministry of Agriculture of the Republic of Kazakhstan (grant no. BR10764960). Physicochemical studies were carried out using the equipment of the Spectro-Analytical Center of the Federal Research Center “Kazan Scientific Center of the Russian Academy of Sciences” within the framework of the state task.

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Authors and Affiliations

  1. Kazakh National Women‘s Teacher Training University, 050000, Almaty, Kazakhstan

    A. B. Kuandykova & B. Zh. Dzhiembaev

  2. A.E. Arbuzov Institute of Organic and Physical Chemistry, Federal Research Center “Kazan Scientific Center of the Russian Academy of Sciences”, 420088, Kazan, Russia

    A. R. Burilov, E. A. Chugunova & A. B. Dobrynin

  3. Korkyt Ata Kyzylorda University, 120014, Kyzylorda, Kazakhstan

    N. I. Akylbekov & G. M. Abyzbekova

Authors
  1. A. B. Kuandykova
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  2. B. Zh. Dzhiembaev
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  3. A. R. Burilov
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  4. N. I. Akylbekov
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  5. E. A. Chugunova
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  6. A. B. Dobrynin
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  7. G. M. Abyzbekova
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Corresponding author

Correspondence to N. I. Akylbekov.

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A.R. Burilov is a member of the Editorial Board of the Russian Journal of General Chemistry. The other authors declare no conflicts of interest.

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Kuandykova, A.B., Dzhiembaev, B.Z., Burilov, A.R. et al. Synthesis of New Symmetrical Diamidophosphates Based on meta-Phenylenediamine under Microwave Irradiation. Russ J Gen Chem 93, 1386–1390 (2023). https://doi.org/10.1134/S1070363223060099

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  • DOI: https://doi.org/10.1134/S1070363223060099

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