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Heterogeneous Fe3O4@Si–NHC–Pd Catalyst: Synthesis, Characterization, and Catalytic Activity in the Suzuki–Miyaura Cross-Coupling Reaction under Mild Conditions

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Abstract

A novel Fe3O4@Si–NHC–Pd catalyst with N-heterocyclic carbenes (NHCs) moiety as an alternative ligand to phosphines for metal complexes has been synthesized and characterized by various methods. Synthesis of metal nanoparticles has been accomplished without aggregation, and the prepared catalyst has been applied in theSuzuki–Miyaura cross-coupling reaction of boronic acids and aryl halides in water using Et3N as a base. The catalyst has demonstrated high efficiency at room temperature and can be easily removed from the reaction media using an external magnetic field and recycled at least five times without significant decrease of its activity.

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ACKNOWLEDGMENTS

We gratefully appreciate the financial support from the Research Council of the K. N. Toosi University of Technology and Iran National Science Foundation.

Funding

This work was supported financially by K. N. Toosi University of Technology Research Council and Iran National Science Foundation (INSF).

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Authors and Affiliations

  1. Department of Organic Chemistry, Faculty of Chemistry, K. N. Toosi University of Technology, P.O. Box, 15875-4416, Tehran, Iran

    R. Ghavidel Kalishomi & S. Rostamizadeh

Authors
  1. R. Ghavidel Kalishomi
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  2. S. Rostamizadeh
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Correspondence to S. Rostamizadeh.

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Kalishomi, R.G., Rostamizadeh, S. Heterogeneous Fe3O4@Si–NHC–Pd Catalyst: Synthesis, Characterization, and Catalytic Activity in the Suzuki–Miyaura Cross-Coupling Reaction under Mild Conditions. Russ J Gen Chem 91, 1140–1146 (2021). https://doi.org/10.1134/S1070363221060244

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