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Interaction of Poly(benzoyl thiocarbamate)-Modified Hyperbranched Polyester with Co(II) and Cu(II) Nitrates

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Abstract

The interaction of Co(NO3)2 and Cu(NO3)2 with hyperbranched polyester containing 7 terminal benzoyl thiocarbamate groups has been studied by IR-Fourier and electron absorption spectroscopy. А new polynuclear complexes of Co(II) and Cu(II) with poly(benzoyl thiocarbamate)-modified hyperbranched polyester have been synthesized. It has been found that the oxygen and sulfur atoms of the peripheral benzoyl thiocarbamate fragments of the macroligand are involved in coordination with metal ions, the metal to ligand ratio being 7 : 1.

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REFERENCES

  1. Popova, N.N., Zhilov, V.I., Tsivadze, A.Y., and Demin, S.V., Russ. J. Inorg. Chem., 2015, vol. 60, no. 6, p. 754. https://doi.org/10.1134/S003602361506011X

    Article  CAS  Google Scholar 

  2. Turanov, A.N., Karandashev, V.K., Baulin, V.E., Kalashnikova, I.P., Tsivadze, A.Y., Kirillov, E.V., Kirillov, S.V., and Rychkov, V.N., Russ. J. Inorg. Chem., 2016, vol. 61, no. 3, p. 377. https://doi.org/10.1134/S0036023616030232

    Article  CAS  Google Scholar 

  3. Kuz’min, V.I., Kuz’mina, V.N., Kuznetsov, P.N., and Kolesnikova, S.M., Solid Fuel Chemistry, 2016, vol. 50, no. 2, p. 120. https://doi.org/10.3103/S036152191602004X

    Article  CAS  Google Scholar 

  4. Ehrlich, G.V. and Lisichkin, G.V., Russ. J. Gen. Chem., 2017, vol. 87, no. 6, p. 1220. https://doi.org/10.1134/S1070363217060196

    Article  CAS  Google Scholar 

  5. Turanov, A.N., Karandashev, V.K., Kharlamov, A.V., and Bondarenko, N.A., Russ. J. Inorg. Chem., 2018, vol. 63, no. 12, p. 1673. https://doi.org/10.1134/S0036023618120203

    Article  CAS  Google Scholar 

  6. Safiulina, A.M., Ivanets, D.V., Kudryavtsev, E.M., Baulin, D.V., Baulin, V.E., and Tsivadze, A.Y., Russ. J. Inorg. Chem., 2019, vol. 64, p. 536. https://doi.org/10.1134/S0036023619040181

    Article  CAS  Google Scholar 

  7. Quas, L., Schrӧder, U., Schrӧder, B., Dietze, F., and Beyer, L., Solv. Extr. Ion. Exch., 2000, vol. 18, no. 6, p. 1167. https://doi.org/10.1080/07366290008934727

    Article  CAS  Google Scholar 

  8. Quas, L., Ristau, T., Schrӧder, U., Dietze, F., Beyer, L., and Anorg, Z., Allg. Chem., 2001, vol. 627, p. 1909

    Article  CAS  Google Scholar 

  9. Hakan, A., Ulrich, F., and Nevzat, K., Spectr. Acta, 2007, vol. 67, p. 936. https://doi.org/10.1016/j.saa.2006.09.011

    Article  CAS  Google Scholar 

  10. Oba, M. and Nishiyama, K., Synthesis, 1994, no. 6, p. 624. https://doi.org/10.1055/s-1994-25536

    Article  Google Scholar 

  11. Schrӧder, U., Beyer, L., Dietze, F., Richter, R., Schmidt, S., and Hoyer, E., J. Prakt. Chem., 1995, vol. 337, p. 184.

    Article  Google Scholar 

  12. Bogdanov, O.S., Vainshenker, I.A., Podnek, A.K., Ryaboi, V.I., and Yanis, N.A., Tsvet. Metal., 1976, p. 72.

  13. Ryaboi, V.I., Kretov, V.P., and Smirnova, E.Yu., Obogashch. Rud, 2013, no. 2, p. 17.

    Google Scholar 

  14. Ribeiro da Silva, M.A.V., Santos, L.M.N.B.F., Schrӧder, B., Dietze, F., and Beyer, L., J. Chem. Thermodyn., 2004, vol. 36, p. 491. https://doi.org/10.1016/j.jct.2004.03.004

    Article  CAS  Google Scholar 

  15. Shirokova, A.G., Pasechnik, L.A., and Yatsenko, S.P., Bull. Russ. Acad. Sci. Physics, 2012, vol. 76, no. 5, p. 604. https://doi.org/10.3103/S106287381205022X

    Article  CAS  Google Scholar 

  16. Sorokina, N.M. and Tsizin, G.I., Vestn. Mosk. Gos. Univ, Ser. 2: Khim., 2016, vol. 57, no. 3, p. 167

    CAS  Google Scholar 

  17. Zonkhoeva, E.L. and Dampilova, B.V., Sorbts. Khromatograf. Protses., 2017, vol. 17, no. 5, p. 797

    CAS  Google Scholar 

  18. Artamonov, A.V., Smirnova, D.N., Smirnov, N.N., and Il’in, A.P., Izv. Vuzov, Ser. Khim. Khim. Tekhnol., 2017, vol. 60, no. 10, p. 87. https://doi.org/10.6060/tcct.20176010.5571

    Article  CAS  Google Scholar 

  19. Turanov, A.N., Karandashev, V.K., and Bondarenko, N.A., Russ. J. Inorg. Chem., 2018, vol. 63, no. 1, p. 128. https://doi.org/10.1134/S0036023618010205

    Article  CAS  Google Scholar 

  20. Oborina, E.N. and Vlasova, N.N., Fizikokhim. Poverkhn. Zashhit. Mater., 2018, vol. 54, no. 4, p. 405. https://doi.org/10.7868/S0044185618040125

    Article  Google Scholar 

  21. Troshkina, I.D., Obruchnikova, Ya.A., and Pestov, S.M., Russ. J. Gen. Chem., 2019, vol. 89, no. 12, vol. 61, no. 4, p. 2721. https://doi.org/10.1134/S107036321912048X

    Article  CAS  Google Scholar 

  22. Kutyreva, M.P., Babkina, S.S., Atanasyan, T.K., Ulakhovich, N.A., and Kutyrev, G.A., Novye materialy: biologicheski aktivnye giperrazvetvlennye polimery i ikh metallokompleksy (New Materials: Biologically Active Hyperbranched Polymers and Their Metal Complexes), Moscow: MGPU, 2014.

  23. Нaüβler, M., Dong, H., and Tang, B.Z., Inorganic and Organometallic Macromolecules: Design and Applications, 2008, p. 21

  24. Seiler, M., Rolker, J., and Arlt, W., Macromolecules, 2003, vol. 36, no. 6, p. 2085. https://doi.org/10.1021/ma025994n

    Article  CAS  Google Scholar 

  25. Jang, J.G. and Bae, Y.C., J. Chem. Phys., 2001, vol. 114, no. 11, p. 5034. https://doi.org/10.1063/1.1329647

    Article  CAS  Google Scholar 

  26. Korolev, V.G. and Bubnova, M.L., Giperrazvetvlennye polimery: novyi moshchnyi stimul dal’neishego razvitiya oblasti trehhmernoi polimerizatsii i revolyutsiya v polimernom materialovedenie (Hyperbranched Polymers: A New Powerful Incentive for the Further Development of the Field of Three-Dimensional Polymerization and the Revolution in Polymer Materials Science), Moscow: IPHF RAN, 2006.

  27. Zagar, E. and Zigon, M., Progress Polymer Sci., 2011, vol. 36, no. 1, p. 53. https://doi.org/10.1016/j.progpolymsci.2010.08.004

    Article  CAS  Google Scholar 

  28. Reul, R., Nguyen, J., and Kissel, T., J. Biomaterial., 2009, vol. 30, no. 29, p. 5815. https://doi.org/10.1016/j.biomaterials.2009.06.057

    Article  CAS  Google Scholar 

  29. Chen, Z., Meng, H., and Xing, G., Toxicology Lett., 2006, vol. 163, no. 2, p. 109. https://doi.org/10.1016/j.toxlet.2005.10.003

    Article  CAS  Google Scholar 

  30. Kutyreva, M.P., Nizamov, I.S., Ulakhovich, N.A., Gataulina, A.R., and Kutyrev, G.A., Russ. J. Gen. Chem., 2011, vol. 81, no. 5, p. 960. https://doi.org/10.1134/S1070363211050227

    Article  CAS  Google Scholar 

  31. Kutyrev, G.A., Maksimov, A.F., Ernandes, A.-M.P., Idiyatov, I.I., Valiullin, L.R., Gallyamova, S.R., Biryulya, V.V., Gataulina, A.R., and Kutyreva, M.P., Vestn. Kazan. Tekhnol. Univ., 2017, vol. 20, no. 20, p. 16.

    CAS  Google Scholar 

  32. Kutyrev, G.A., Busygina, A.A., Akhmadulina, E.N., Rakhmadullina, L.R., Kutyreva, M.P., and Gataulina, A.R., Vestn. Kazan. Tekhnol. Univ., 2016, vol. 19, no. 14, p. 15.

    CAS  Google Scholar 

  33. Vallejos, S.T., Erben, M.F., Piro, O.E., Castellano, E.E., and Della Védova, C.O., Polyhedron, 2009, vol. 28, p. 937. https://doi.org/10.1016/j.poly.2009.01.022

    Article  CAS  Google Scholar 

  34. Faizi, S., Siddiqui, B.S., Saleem, R., Siddiqui, S., Aftab, K., and Gilani, A.U.H., J. Chem. Soc. Perkin Trans., 1992, vol. 1, p. 3237.

    Article  Google Scholar 

  35. Faizi, S., Siddiqui, B.S., Saleem, R., Siddiqui, S., Aftab, K., and Gilani, A.U.H., J. Chem. Soc. Perkin Trans., 1994, vol. 1, p. 3035. https://doi.org/10.1039/P19940003035

    Article  Google Scholar 

  36. Faizi, S., Siddiqui, B.S., Saleem, R., Noor, F., and Husnain, S., J. Nat. Prod., 1997, vol. 60, no. 12, p. 1317. https://doi.org/10.1021/np970038y

    Article  CAS  Google Scholar 

  37. Faizi, S., Siddiqui, B.S., Saleem, R., Siddiqui, S., Aftab, K., and Gilani, A.U.H., Phytochem., 1995, vol. 38, p. 957. https://doi.org/10.1016/0031-9422(94)00729-D

    Article  CAS  Google Scholar 

  38. Trivedi, B.K., US Patent 8810816, 1988; C. A., 1988, vol. 108, 167428d

  39. Kutyrev, G.A., Maksimov, A.F., Ernandes, A.-M.P., Kutyreva, M.P., and Gataulina, A.R., Vestn. Kazan. Tekhnol. Univ., 2018, vol. 21, no. 19, p. 69.

    Google Scholar 

  40. Beck, M. and Nadpal, I., The Investigation of Complexation with the Latest Methods, Moscow: Mir, 1989.

  41. Basha, M.T., Alghanmi, R.M., Shehata, M.R., and Abdel-Rahman, L.H., J. Mol. Struct., 2019, vol. 1183, p. 298. https://doi.org/10.1016/j.molstruc.2019.02.001

    Article  CAS  Google Scholar 

  42. Liver, E., Electron Spectroscopy of Inorganic Compounds, Moscow: Mir, 1987.

  43. Tang, Q., Zhang, Q., Wu, H., and Wang, Y., J. Catal., 2005, vol. 230, p. 384. https://doi.org/10.1016/j.jcat.2004.12.017

    Article  CAS  Google Scholar 

  44. Bondar, O.V., Gataulina, A.R., Ulakhovich, N.A., and Kutyreva, M.P., Russ. J. Org. Chem., 2018, vol. 54, no. 9, p. 1301. https://doi.org/10.1134/S1070428018090051

    Article  CAS  Google Scholar 

  45. Medvedeva, O.I., Kambulova, S.S., Ulakhovich, N.A., Vorobev, V.V., Evtyugin, V.G., Khaldeeva, E.V., and Kutyreva, M.P., Russ. J. Gen. Chem., 2017, vol. 87, no. 9, p. 1985. https://doi.org/10.1134/S1070363217090146

    Article  CAS  Google Scholar 

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Kutyreva, M.P., Maksimov, A.F., Ernandes, A.M.P. et al. Interaction of Poly(benzoyl thiocarbamate)-Modified Hyperbranched Polyester with Co(II) and Cu(II) Nitrates. Russ J Gen Chem 90, 268–273 (2020). https://doi.org/10.1134/S1070363220020164

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