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Synthesis, structure, and properties of nickel complexes with nitrilotris(methylenephosphonic acid) [Ni(H2O)3N(CH2PO3H)3] and Na4[Ni(H2O)N(CH2PO3)3] ∙ 11H2O

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Abstract

Nitrilotris(methylenephosphonato)triaquanickel and tetrasodium nitrilotris(methylenephosphonato) aquanickelate undecahydrate were synthesized and characterized. The crystal of [Ni(H2O)3N(CH2PO3H)3] is composed of linear coordination polymers and belongs to sp. gr. P21/c, Z = 4, a = 9.17120(10) Å, b = 16.05700(10) Å, c = 9.70890(10) Å, β = 115.830(2)°. The Ni atom is in an octahedral coordination formed by two oxygen atoms of one phosphonate ligand, one oxygen atom of another ligand molecule, and three water molecules in a meridional configuration. The crystal of Na4[Ni(H2O)N(CH2PO3)3] ∙ 11H2O has an island dimeric chelate structure and belongs to sp. gr. С2/c, Z = 8, a = 18.7152(2) Å, b = 12.05510(10) Å, c = 21.1266(2) Å, β = 104.4960(10)°. The Ni atom has a slightly distorted octahedral coordination involving one nitrogen atom and closes three five-membered N–C–P–O–Ni rings sharing the Ni–N bond.

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Authors and Affiliations

  1. Lobachevsky Nizhny Novgorod State University, Gagarina pr. 23, Nizhny Novgorod, 603950, Russia

    N. V. Somov

  2. Physico-Technical Institute, Ural Branch, Russian Academy of Sciences, ul. Kirova 132, Izhevsk, 426000, Russia

    F. F. Chausov

  3. Udmurt State University, ul. Universitetskaya 1, Izhevsk, 426034, Russia

    F. F. Chausov, R. M. Zakirova & I. V. Fedotova

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  1. N. V. Somov
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  2. F. F. Chausov
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  3. R. M. Zakirova
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  4. I. V. Fedotova
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Correspondence to N. V. Somov.

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Original Russian Text © N.V. Somov, F.F. Chausov, R.M. Zakirova, I.V. Fedotova, 2016, published in Kristallografiya, 2016, Vol. 61, No. 2, pp. 238–246.

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Somov, N.V., Chausov, F.F., Zakirova, R.M. et al. Synthesis, structure, and properties of nickel complexes with nitrilotris(methylenephosphonic acid) [Ni(H2O)3N(CH2PO3H)3] and Na4[Ni(H2O)N(CH2PO3)3] ∙ 11H2O. Crystallogr. Rep. 61, 216–224 (2016). https://doi.org/10.1134/S1063774516020243

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