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The Adsorption of 5,10,15,20-Tetrakis(N-methylpyridyl-4')porphine Tetratosylate on the Surface of Nickel from an Aqueous Solution

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Abstract

Macroheterocyles, such as porphyrins, phthalocyanines, and their coordination compounds, introduced into standard electrolytes for nickel plating and electroplating of Ni–Co and Ni–Fe alloys substantially improve the quality of coatings. The adsorption of 5,10,15,20-tetrakis(N-methylpyridyl-4')porphine tetratosylate on the surface of Ni is studied via ellipsometry and X-ray photoelectron spectroscopy (XPS).

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ACKNOWLEDGMENTS

This work was supported by the Russian Science Foundation (agreement no. 14-23-00204, grant no. 16-03-00646) and within the framework of the execution of a state order of the Ministry of Education and Science of the Russian Federation to institutions of higher education.

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Authors and Affiliations

  1. A.N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, 119071, Moscow, Russia

    N. P. Andreeva, O. Yu. Grafov, L. P. Kazanskii & Yu. I. Kuznetsov

  2. Scientific and Research Institute of Macroheterocycles, Ivanovo State University of Chemistry and Technology, 153000, Ivanovo, Russia

    A. V. Larionov & O. A. Golubchikov

Authors
  1. N. P. Andreeva
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  2. A. V. Larionov
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  3. O. Yu. Grafov
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  4. O. A. Golubchikov
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  5. L. P. Kazanskii
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  6. Yu. I. Kuznetsov
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Correspondence to N. P. Andreeva.

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Translated by E. Boltukhina

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Andreeva, N.P., Larionov, A.V., Grafov, O.Y. et al. The Adsorption of 5,10,15,20-Tetrakis(N-methylpyridyl-4')porphine Tetratosylate on the Surface of Nickel from an Aqueous Solution. Prot Met Phys Chem Surf 54, 1276–1283 (2018). https://doi.org/10.1134/S2070205118070031

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  • DOI: https://doi.org/10.1134/S2070205118070031

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