Abstract
Cost-effective, safe, and efficient technology for obtaining powder compositions of polydisperse iron oxides with carbon by reducing nanosized raw material with solid carbon has been developed. The use of the powder composition as a nonseparable activator of cementation of high-salt boron-containing liquid radioactive waste (LRW) from a nuclear power plant (NPP) instead of the previously used powder containing nanoscale iron reduces the setting time of the compounds from 56 to 2 days, reduces the volume of conditioned LRW 3–5 times, reduces the technological cycle of the waste disposal, and improves the strength characteristics of hardened cement compounds; this makes the recycling process more cost-effective.
Similar content being viewed by others
REFERENCES
V. A. Avramenko, A. M. Egorin, E. K. Papynov, T. A. Sokolitskaya, I. G. Tananaev, and V. I. Sergienko, “Processes for treatment of liquid radioactive waste containing seawater,” Radiochemistry 59, 407 (2017).
N. Yu. Anisimov, K. S. Golokhvast, and I. G. Tananaev, “The development and role of radioecology in the far east: problems and solutions,” Vopr. Rad. Bezopasn., No. 4, 3–9 (2017).
M. A. Fedotov, O. A. Gorbunova, O. V. Fedorova, G. E. Folmanis, and L. V. Kovalenko, “Magnetic iron oxides in the cementation technology of the boron-containing radioactive waste,” Mater. Sci. Eng. 81, 012063 (2015).
O. A. Gorbunova and T. S. Kamaeva, “Physical and chemical methods of controlling the properties of cement compounds with boron-containing liquid radioactive waste,” Fiz. Khim. Obrab. Mater., No. 1, 69–76 (2013).
T. S. Kamaeva, “Cementing boron-containing LRW using vortex electromagnetic treatment with nanoactivators,” in Collection of Articles of Young Scientists of Vernadsky Inst. Geochem. Anal. Chem. (GEOKhI RAN, Moscow, 2011), p. 24 [in Russian].
O. A. Gorbunova, T. S. Kamaeva, and E. V. Vasil’ev, “The use of nanoparticles of iron oxide when cementing liquid with raw vortex electromagnetic processing,” Vestn. MGSU, No. 5, 208–213 (2011).
O. A. Gorbunova, T. S. Kamaeva, I. G. Tananaev, G. E. Folmanis, B. F. Myasoedov, and Yu. M. Kulyako, “The method of conditioning liquid radioactive waste,” RF Patent No. 2516235, Byull. Izobret., No. 14, 9 (2014).
A. N. Krutilin, M. N. Kukharchuk, and O. A. Sycheva, “Solid phase reduction of iron oxides by carbon,” Lit’e Metall., No. 2, 11–16 (2012).
ACKNOWLEDGMENTS
This work was financially supported by the Russian Foundation for Basic Research, project no. 19-03-00119-a, as part of Baikov Institute of Metallurgy and Materials Science State Contract no. 007-00129-18-00.
Author information
Authors and Affiliations
Corresponding author
Additional information
Translated by D. Kharitonov
Rights and permissions
About this article
Cite this article
Fedotov, M.A., Kovalenko, L.V., Folmanis, G.E. et al. Functional Materials for Radioactive Waste Management. Nanotechnol Russia 13, 578–584 (2018). https://doi.org/10.1134/S199507801806006X
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S199507801806006X