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Effect of heterocyclic derivatives of ferrocene on free-radical polymerization of methyl methacrylate and styrene

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Abstract

The free-radical bulk homopolymerization of methyl methacrylate and styrene initiated by benzoyl peroxide or AIBN in the presence of heterocyclic derivatives of ferrocene is studied. It is shown that, in the case of the peroxide initiator, ferrocene derivatives form highly efficient initiation systems, which make it possible to polymerize methyl methacrylate at a high rate, to reduce the molecular mass of polymers, and to synthesize polymers with a high content of syndiotactic triads, while in the case of AIBN, such systems are not formed.

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Authors and Affiliations

  1. Institute of Organic Chemistry, Ufa Research Center, Russian Academy of Sciences, pr. Oktyabrya 71, Ufa, 450054, Bashkortostan, Russia

    R. M. Islamova, O. I. Golovochesova & Yu. B. Monakov

  2. Ural State Technical University, ul. Mira 19, Yekaterinburg, 620002, Russia

    I. A. Utepova, A. A. Musikhina & O. N. Chupakhin

  3. Institute of Organic Synthesis, Ural Division, Russian Academy of Sciences, ul. Sofii Kovalevskoi 22, Yekaterinburg, 620041, Russia

    O. N. Chupakhin

Authors
  1. R. M. Islamova
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  2. O. I. Golovochesova
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  3. Yu. B. Monakov
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  4. I. A. Utepova
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  5. A. A. Musikhina
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  6. O. N. Chupakhin
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Corresponding author

Correspondence to R. M. Islamova.

Additional information

Original Russian Text © R.M. Islamova, O.I. Golovochesova, Yu.B. Monakov, I.A. Utepova, A.A. Musikhina, O.N. Chupakhin, 2010, published in Russian in Vysokomolekulyarnye Soedineniya, Ser. B, 2010, Vol. 52, No. 12, pp. 2184–2194.

This work was supported by the Russian Foundation for Basic Research (project nos. 10-03-00027-a and 07-03-96104r_ural_a) and a grant from the president of the Russian Federation for Supporting Young Scientists (project MK-4166.2009.3).

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Islamova, R.M., Golovochesova, O.I., Monakov, Y.B. et al. Effect of heterocyclic derivatives of ferrocene on free-radical polymerization of methyl methacrylate and styrene. Polym. Sci. Ser. B 52, 637–647 (2010). https://doi.org/10.1134/S1560090410110023

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  • DOI: https://doi.org/10.1134/S1560090410110023

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