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Copolymerization of 2,2-diallyl-1,1,3,3-tetraethylguanidinium chloride with N-substituted maleimides

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Abstract

The free-radical copolymerization of 2,2-diallyl-1,1,3,3-tetraethylguanidinium chloride with N-phenyl- and N-p-carboxyphenylmaleimide is studied in bulk and in organic solvents. It is shown that copolymerization proceeds to form copolymers with a high tendency toward alternation of monomer units. The kinetic laws of the reaction are investigated, and the relative activities of the monomers are determined. It is found that 2,2-diallyl-1,1,3,3-tetraethylguanidinium chloride is involved in copolymerization with N-substituted maleimides to give rise to pyrrolidinium structures. This work was supported by the Russian Foundation for Basic Research (project no. 09-03-00220) and the by the Presidium of the Russian Academy of Sciences through the program Development of Methods of Synthesis of Chemical Substances and the Creation of Novel Materials.

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Authors and Affiliations

  1. Institute of Technical Chemistry, Ural Division, Russian Academy of Sciences, ul. Akademika Koroleva 3, Perm, 614013, Russia

    M. N. Gorbunova

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Original Russian Text © M.N. Gorbunova, 2010, published in Russian in Vysokomolekulyarnye Soedineniya, Ser. B, 2010, Vol. 52, No. 8, pp. 1515–1522.

This work was supported by the Russian Foundation for Basic Research (project no. 09_03_00220) and the by the Presidium of the Russian Academy of Sciences through the program Development of Methods of Synthesis of Chemical Substances and the Creation of Novel Materials.

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Gorbunova, M.N. Copolymerization of 2,2-diallyl-1,1,3,3-tetraethylguanidinium chloride with N-substituted maleimides. Polym. Sci. Ser. B 52, 473–479 (2010). https://doi.org/10.1134/S1560090410070122

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  • DOI: https://doi.org/10.1134/S1560090410070122

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