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Synthesis of 3-R-Sulfanyl-5-amino-1-phenyl-1H-pyrazole-4-Carbonitriles

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Abstract

Previously unknown 3-R-sulfanyl-5-amino-1-phenyl-1H-pyrazole-4-carbonitriles were synthesized by reactions of 2-[bis(alkylsulfanyl)methylidene]malononitriles with phenylhydrazine. A similar reaction with 2-(1,3-dithiolan-2-ylidene)malononitrile afforded 3,3′-{disulfanediylbis[(ethane-2,1-diyl)sulfanediyl]}bis-(5-amino-1-phenyl-1H-pyrazol-4-carbonitrile).

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Acknowledgments

A part of the study was performed in the framework of state assignment to the Institute of General and Inorganic Chemistry (Russian Academy of Sciences) in the field of basic research.

Funding

This study was performed under financial support by the President of the Russian Federation (program for state support of young Russian scientists, contract no. 075-15-2019-737, project no. MK-5518.2018.3).

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Authors and Affiliations

  1. I.N. Ul’yanov Chuvash State University, Cheboksary, 428015, Russia

    K. V. Lipin, O. V. Ershov & S. V. Fedoseev

  2. Kurnakov Institute of General and Inorganic Chamistry, Russian Academy of Sciences, Moscow, 119991, Russia

    A. A. Mikhailov

Authors
  1. K. V. Lipin
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  2. O. V. Ershov
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  3. S. V. Fedoseev
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  4. A. A. Mikhailov
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Corresponding author

Correspondence to K. V. Lipin.

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The authors declare the absence of conflict of interest.

Additional information

Russian Text © The Author(s), 2020, published in Zhurnal Organicheskoi Khimii, 2020, Vol. 56, No. 1, pp. 144–147.

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Lipin, K.V., Ershov, O.V., Fedoseev, S.V. et al. Synthesis of 3-R-Sulfanyl-5-amino-1-phenyl-1H-pyrazole-4-Carbonitriles. Russ J Org Chem 56, 177–180 (2020). https://doi.org/10.1134/S1070428020010273

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  • DOI: https://doi.org/10.1134/S1070428020010273

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