Abstract
Condensation of substituted benzaldehydes of vanillin series with dimedone in methanol solution in the presence of catalytic quantities of triethylamine afforded 2,2′-arylmethylenebis(3-hydroxy-5,5-dimethylcyclohex-2-en-1-ones. By catalytic cyclization of the latter in boiling benzene in the presence of sulfo cation exchanger FIBAN K-1 as catalyst 3,3,6,6-trimethyl-9-aryl-3,4,5,6,7,9-hexahydro-1H-xanthene-1,8(2H)-diones were synthesized.
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Original English Text © E.A. Dikusar, V.I. Potkin, N.G. Kozlov, A.S. Pavlyuchenkova, M.Yu. Murashova, S.K. Petkevich, A.V. Kletskov, A.P. Polikarpov, M.M. Ogorodnikova, R.M. Zolotar’, O.P. Chepik, 2013, published in Zhurnal Organicheskoi Khimii, 2013, Vol. 49, No. 2, pp. 243–251.
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Dikusar, E.A., Potkin, V.I., Kozlov, N.G. et al. Catalytic synthesis of 2,2′-arylmethylenebis(3-hydroxy-5,5-dimethylcyclohex-2-en-1-ones) and 3,3,6,6-tetramethyl-9-aryl-3,4,5,6,7,9-hexahydro-1H-xanthene-1,8(2H)-diones. Russ J Org Chem 49, 233–242 (2013). https://doi.org/10.1134/S1070428013020103
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DOI: https://doi.org/10.1134/S1070428013020103