Abstract
Reactions of commercial polychlorobiphenyl mixtures with alkali in polyalkanolamines were studied. The major reaction products are hydrophilic mixtures of hydroxy derivatives of polychlorobiphenyls. The highest conversion of commercial polychlorobiphenyl mixtures was reached when using 2-aminoethanol. This reaction can be used as the step of pretreatment of technogenic waste prior to microbiological degradation.
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Acknowledgments
The study was performed using the equipment of the Center for Shared Use Spectroscopy and Analysis of Organic Compounds.
Funding
The study was financially supported by the Russian Foundation for Basic Research (project no. 18-29-05016 mk).
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The authors declare that they have no conflict of interest.
Russian Text © The Author(s), 2019, published in Zhurnal Prikladnoi Khimii, 2019, Vol. 92, No. 7, pp. 947–952.
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Gorbunova, T.I., Pervova, M.G., Saloutin, V.I. et al. Reagent Pretreatment of Polychlorobiphenyls prior to Breakdown. Russ J Appl Chem 92, 1039–1044 (2019). https://doi.org/10.1134/S1070427219070218
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DOI: https://doi.org/10.1134/S1070427219070218