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Catalytic Activity of Polyfunctional Ionic Liquids in Oxidation of Model Sulfur Organic Compounds

  • Catalysis
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Abstract

Ionic liquids based on 1-methylimidazole were synthesized. The liquids contain Bronsted acid centers in the cation and a transition metal atom in the anion. The polyfunctional ionic liquids synthesized in the study are effective catalysts for the oxidative desulfurization process. The conditions are found for reaching the 100% conversion of methyl phenyl sulfide under mild conditions in the presence of the catalysts, ionic liquids [ionic liquid: 3-(carboxymethyl)-1-methyl-1H-imidazol-3-ium molybdate with S: Mo molar ratio = 24 ∶ 1, 2 h, 40°C, H2O2: S molar ratio = 12 ∶ 1].

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Authors and Affiliations

  1. Chemical Faculty, Lomonosov Moscow State University, Moscow, 119234, Russia

    A. V. Akopyan, E. A. Eseva, P. D. Polikarpova, T. M. Baigil’diev, I. A. Rodin & A. V. Anishnov

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  1. A. V. Akopyan
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  2. E. A. Eseva
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  3. P. D. Polikarpova
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  4. T. M. Baigil’diev
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  5. I. A. Rodin
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  6. A. V. Anishnov
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Correspondence to A. V. Akopyan.

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Russian Text © The Author(s), 2019, published in Zhurnal Prikladnoi Khimii, 2019, Vol. 92, No. 4, pp. 531−537.

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Akopyan, A.V., Eseva, E.A., Polikarpova, P.D. et al. Catalytic Activity of Polyfunctional Ionic Liquids in Oxidation of Model Sulfur Organic Compounds. Russ J Appl Chem 92, 569–575 (2019). https://doi.org/10.1134/S1070427219040141

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  • DOI: https://doi.org/10.1134/S1070427219040141

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