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Specific structural features of crystalline regions in biodegradable composites of poly-3-hydroxybutyrate with chitosan

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Abstract

Differential scanning calorimetry and X-ray diffraction at wide and small angles were used to examine the biodegradable composites of poly-3-hydroxybutyrate with chitosan, produced by mixing of these polymers in a rotor disperser at 150°C. Samples of individual polymers and composites with 80, 40, and 20 wt % poly- 3-hydroxybutyrate were studied. It was found that the presence of chitosan in the composites leads to a change in the crystallite size of poly-3-hydroxybutyrate and to an increase in the large period in this polymer. Mixing of poly-3-hydroxybutyrate with chitosan affects the structural rearrangement in crystalline regions of poly-3-hydroxybutyrate under a high-temperature treatment. The effect of a high-temperature treatment of the composites via alternation of melting–crystallization cycles in the nonisothermal mode, when a sample is heated and cooled at the same constant rate of 8 deg min–1 in the range from 20 to 200°C and is annealed at a temperature of 150°C, was analyzed. This analysis suggests that, in composites of this kind, the intermolecular interaction between the components is a factor strongly affecting the structure of the crystalline regions and the mechanism of their rearrangement in the course of annealing. The mechanism of this interaction is discussed.

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Authors and Affiliations

  1. Emanuel Institute of Biochemical Physics, Russian Academy of Sciences, ul. Kosygina 4, Moscow, 119334, Russia

    L. S. Shibryaeva, O. V. Shatalova, A. V. Krivandin, Yu. V. Tertyshnaya & Yu. V. Solovova

  2. Federal Agroengineering Research Center VIM, 1-i Institutskii pr. 5, Moscow, 109428, Russia

    L. S. Shibryaeva & Yu. V. Tertyshnaya

Authors
  1. L. S. Shibryaeva
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  2. O. V. Shatalova
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  3. A. V. Krivandin
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  4. Yu. V. Tertyshnaya
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  5. Yu. V. Solovova
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Correspondence to L. S. Shibryaeva.

Additional information

Original Russian Text © L.S. Shibryaeva, O.V. Shatalova, A.V. Krivandin, Yu.V. Tertyshnaya, Yu.V. Solovova, 2017, published in Zhurnal Prikladnoi Khimii, 2017, Vol. 90, No. 9, pp. 1187−1198.

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Shibryaeva, L.S., Shatalova, O.V., Krivandin, A.V. et al. Specific structural features of crystalline regions in biodegradable composites of poly-3-hydroxybutyrate with chitosan. Russ J Appl Chem 90, 1443–1453 (2017). https://doi.org/10.1134/S1070427217090117

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  • DOI: https://doi.org/10.1134/S1070427217090117

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