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Effect of sodium vanadate on corrosion of AD31 aluminum alloy in acid media

  • Inorganic Synthesis and Industrial Inorganic Chemistry
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Abstract

Scanning electron microscopy, potentiodynamic polarization method, and electrochemical impedance spectroscopy were used to study the corrosion behavior of AD31 (AA6063) aluminum alloy in acid (pH 3) 0.05 M NaCl solutions containing 3 mmol dm–3 of NaVO3 inhibitor. It was found that the corrosion of AD31 alloy in acid sodium chloride solutions predominantly occurs locally at aluminum/intermetallic particle phase boundaries and is limited by the electrochemical stage of charge transfer. It was shown that introduction of sodium vanadate can reduce the rate of selective dissolution of magnesium from the alloy and provides a protective effect on the level of 7–10%.

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Authors and Affiliations

  1. Belarusian State Technological University, ul. Sverdlova 13a, Minsk, 220006, Belarus

    D. S. Kharitonov, I. I. Kurilo & I. M. Zharskii

  2. KTH Royal Institute of Technology, Stockholm, Sweden

    D. S. Kharitonov

Authors
  1. D. S. Kharitonov
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  2. I. I. Kurilo
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  3. I. M. Zharskii
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Correspondence to D. S. Kharitonov.

Additional information

Original Russian Text © D.S. Kharitonov, I.I. Kurilo, I.M. Zharskii, 2017, published in Zhurnal Prikladnoi Khimii, 2017, Vol. 90, No. 7, pp. 877−885.

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Kharitonov, D.S., Kurilo, I.I. & Zharskii, I.M. Effect of sodium vanadate on corrosion of AD31 aluminum alloy in acid media. Russ J Appl Chem 90, 1089–1097 (2017). https://doi.org/10.1134/S1070427217070102

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  • DOI: https://doi.org/10.1134/S1070427217070102

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