Skip to main content
SpringerLink
Log in

Co-Mo/Al2O3 and Ni-W/Al2O3 catalysts: Potential and prospects for use in hydrotreating of light cycle oil from catalytic cracking

  • Catalysis
  • Published:
Russian Journal of Applied Chemistry Aims and scope Submit manuscript

Abstract

Со-Мо/Al2O3 and Ni-W/Al2O3 catalysts were tested in hydrotreating of light cycle oil from catalytic cracking, of the straight-run gasoil, and of their mixture under typical hydrotreating conditions used in industry. The catalysts prepared using PMo12 and PW12 heteropoly acids exhibit high catalytic activity. The Со-Мо/Al2O3 catalyst is more active in hydrodesulfurization and hydrogenation of olefin and diene hydrocarbons, whereas the Ni-W/Al2O3 catalysts are more active in hydrogenation of mono- and polycyclic aromatic hydrocarbons. Comparison of the quality characteristics of the hydrogenizates obtained with the requirements of the technical regulations shows that the required levels of the sulfur content and cetane number of the hydrogenizates at practically accessible process parameters can be reached for mixtures of the straight-run gasoil and light cycle oil from catalytic cracking with high content of the latter component only when the process with the Со-Мо/Al2O3 system and Ni-W/Al2O3 catalysts is performed in two steps.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Requirements to Automobile and Aviation Gasoline, to Diesel and Ship Fuel, to Fuel for Jet Engines, and to Eurnace Mazut, Technical Regulations, Approved by Resolution no. 118 of the Russian Federation Government of February 27, 2008.

  2. Babich, I.V. and Moulijn, J.A., Fuel, 2003, vol. 82, p. 607.

    Article  CAS  Google Scholar 

  3. Dmitrievskii, A.N., Buren. Neft’, 2012, no. 1, pp. 3–12.

    Google Scholar 

  4. Cooper, B.H. and Donnis, B.B.L., Appl. Catal. A: General, 1996, vol. 137, pp. 203–223.

    Article  CAS  Google Scholar 

  5. Rudin, M.G., Karmannyi spravochik neftepererabotchika (Pocket Handbook of Oil Refining Worker), Leningrad: Khimiya, 1989.

    Google Scholar 

  6. Elshin, D.I., Aliev, R.R., Tomin, V.P., and Krashchuk, S.G., Khim. Tekhnol. Topl. Masel, 2005, no. 3, pp. 15–17.

    Google Scholar 

  7. Korneev, D.G., Sovrem. Tend. Razv. Nauki Tekhnol., 2015, nos. 7–8, pp. 53–58.

    Google Scholar 

  8. Pimerzin, A.A., Tomina, N.N., Safronova, T.N., et al., Ross. Khim. Zh. (Zh. Ross. Khim. O–va. im. D.I. Mendeleeva), 2015, vol. 59, nos. 5–6, pp. 42–49.

    Google Scholar 

  9. Mingfeng, L., Huifeng, L., Feng, J., et al., Catal. Today, 2010, vol. 149, pp. 35–39.

    Article  Google Scholar 

  10. ASTM D-5453-16-1 Procedure: Standard Test Method for Determination of Total Sulfur in Light Hydrocarbons, Spark Ignition Engine Fuel, Diesel Engine Fuel, and Engine Oil by Ultraviolet Fluorescence, West Conshohocken, PA: ASTM Int., 2016.

  11. ASTM D-4629-12 Procedure: Standard Test Method for Trace Nitrogen in Liquid Petroleum Hydrocarbons by Syringe/Inlet Oxidative Combustion and Chemiluminescence Detection, West Conshohocken, PA: ASTM Int., 2012.

  12. GOST (State Standard) 2070–82: Light Petroleum Products. Methods for Determining Iodine Numbers and Content of Unsaturated Hydrocarbons, Introduced July 1, 1983, Moscow: Standartinform, 2006.

  13. Krylov, O.V., Geterogennyi kataliz (Heterogeneous Catalysis), Moscow: Akademkniga, 2004.

    Google Scholar 

  14. Tomina, N.N., Pimerzin, A.A., Zhilkina, E.O., and Eremina, Yu.V., Petroleum Chem., 2009, vol. 49, pp. 114–119.

    Article  Google Scholar 

  15. Arribas, M.A., Corma, A., Diaz-Cabanas, M.J., et al., Appl. Catal. A: General, 2004, vol. 273, pp. 277–286.

    Article  CAS  Google Scholar 

  16. Zhorov, Yu.M., Raschety i issledovaniya khimicheskikh protsessov neftepererabotki (Calculations and Studies of Chemical Oil Refining Processes), Moscow: Khimiya, 1973.

    Google Scholar 

  17. Masagutov, R.M., Morozov, B.F., and Kutepov, B.I., Regeneratsiya katalizatorov v neftepererabotke i neftekhimii (Regeneration of Catalysts in Oil Refining and Petroleum Chemistry), Moscow: Khimiya, 1987.

    Google Scholar 

  18. Startsev, A.N., Catal. Today, 2009, vol. 144, pp. 350–357.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Samara State Technical University, Molodogvardeiskaya ul. 244, Samara, 443100, Russia

    N. M. Maximov, N. N. Tomina, P. S. Solmanov & A. A. Pimerzin

Authors
  1. N. M. Maximov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. N. N. Tomina
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. P. S. Solmanov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. A. A. Pimerzin
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to N. M. Maximov.

Additional information

Original Russian Text © N.M. Maximov, N.N. Tomina, P. S. Solmanov, A.A. Pimerzin, 2017, published in Zhurnal Prikladnoi Khimii, 2017, Vol. 90, No. 4, pp. 477−484.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Maximov, N.M., Tomina, N.N., Solmanov, P.S. et al. Co-Mo/Al2O3 and Ni-W/Al2O3 catalysts: Potential and prospects for use in hydrotreating of light cycle oil from catalytic cracking. Russ J Appl Chem 90, 574–581 (2017). https://doi.org/10.1134/S1070427217040139

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070427217040139

Search

Navigation