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Structural-phase state and surface properties of composite materials based on polylactide and hydroxyapatite

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Abstract

The phase composition and unit cell parameters were determined for composites based on polylactide and hydroxyapatite with the polylactide/hydroxyapatite weight ratios of 90/10, 80/20, 70/30, and 60/40. As the polylactide content of the composites is increased, they become less hydrophilic, and the surface energy σS-G increases from 29.13 to 74.35 mJ m–2. The sample with the component weight ratio of 70/30 is characterized by the maximal roughness, and the Ca2+ and Mg2+ ions from simulated body fluid are actively adsorbed onto its surface, as proved by SEM examination of the composites.

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References

  1. Biomaterials, Artificial Organs and Tissue Engineering, Hench, L. and Jones, J., Eds., Woodhead, 2005.

  2. Goswami, J., Bhatnagar, N., Mohanty, S., et al., eXPRESS Polym. Lett., 2013, vol. 7, pp. 767–777.

    Article  CAS  Google Scholar 

  3. Sevast’yanov, V.I. and Kirpichnikov, M.P., Biosovmestimye materialy (Biocompatible Materials), Moscow MIA, 2011.

    Google Scholar 

  4. Diao, H., Si, Y., Zhu, A., et al., Mater. Sci. Eng. C, 2012, vol. 32, pp. 1796–1801.

    Article  CAS  Google Scholar 

  5. Peng, F., Yu, X., and Wei, M., Acta Biomater., 2011, vol. 7, pp. 2585–2592.

    Article  CAS  Google Scholar 

  6. EP Patent 0289562 B1, Finland, Publ. 1993.

  7. Verheyen, C., Klein, C., De Blieck-Hogervorst, J., et al., J. Mater. Sci.: Mater., 1993, vol. 4, pp. 58–65.

    CAS  Google Scholar 

  8. Shikinami, Y. and Okuno, M., Biomaterials, 1999, vol. 20, pp. 859–877.

    Article  CAS  Google Scholar 

  9. Ignjatovic, N., Delijic, K., Vukcevic, M., and Uskokovic, D., Z. Metallkunde, 2001, vol. 92, pp. 145–149.

    CAS  Google Scholar 

  10. Ignjatovic, N., Suljovrujic, E., Stojanovic, Z., and Uskokovic, D., Sci. Sint., 2002, vol. 34, pp. 79–93.

    Article  CAS  Google Scholar 

  11. Furukawa, T., Matsusue, Y., Yasunaga, T., et al., Biomaterials, 2000, vol. 21, pp. 889–898.

    Article  CAS  Google Scholar 

  12. Furukawa, T., Matsusue, Y., Yasunaga, T., et al., J. Biomed. Mater. Res., 2000, vol. 50, pp. 410–419.

    Article  CAS  Google Scholar 

  13. Shapovalova, Y., Lytkina, D., Rasskazova, L., et al., Key Eng. Mater., 2016, vol. 683, pp. 475–480.

    Article  Google Scholar 

  14. Laboratornye raboty i zadachi po kolloidnoi khimii (Laboratory Works and Problems on Colloid Chemistry), Frolov, Yu.G. and Grodskii, A.S., Eds., Moscow, Khimiya, 1986.

  15. Mironyuk, A.V., Pridatko, A.V., Sivolapov, P.V., and Sviderskii, V.A., Tekhnol. Org. Neorg. Veshch., 2014, pp. 23–26.

    Google Scholar 

  16. Takadama, H., Kim, H.M., Kokubo, T., and Nakamura, T., J. Am. Ceram. Soc., 2002, vol. 85, pp. 1933–1936.

    Article  CAS  Google Scholar 

  17. Takadama, H., Kim, H.M., Kokubo, T., and Nakamura, T., J. Biomed. Mater. Res., 2001, vol. 57, pp. 441–448.

    Article  CAS  Google Scholar 

  18. Brizzolara, D. Cantow, H.J., Diederichs, K., et al., Macromolecules, 1996, vol. 29, pp. 191–197.

    Article  CAS  Google Scholar 

  19. Rasskazova, L.A., Lytkina, D.N., Shapovalova, E.G., et al., Russ. J. Appl. Chem., 2015, vol. 88, no. 4, pp. 669–675.

    Article  CAS  Google Scholar 

  20. Ohtsuki, C., Aoki, Y., Kokubo, T., et al., J. Ceram. Soc. Jpn., 1995, vol. 103, pp. 449–454.

    Article  CAS  Google Scholar 

  21. Tanahashi, M. and Matsuda, T., J. Biomed. Mater. Res., 1997, vol. 34, pp. 305–315.

    Article  CAS  Google Scholar 

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Correspondence to V. A. Syusyukina.

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Original Russian Text © V.A. Syusyukina, Ye. Shapovalova, N.M. Korotchenko, I.A. Kurzina, 2017, published in Zhurnal Prikladnoi Khimii, 2017, Vol. 90, No. 1, pp. 114−120.

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Syusyukina, V.A., Shapovalova, Y., Korotchenko, N.M. et al. Structural-phase state and surface properties of composite materials based on polylactide and hydroxyapatite. Russ J Appl Chem 90, 106–112 (2017). https://doi.org/10.1134/S1070427217010165

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  • DOI: https://doi.org/10.1134/S1070427217010165

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