Abstract
Rigid-chain heat resistant polymers (with poly-2,2'-p-oxydiphenylene-5,5′-bisbenzimidazole as example) were impregnated for the first time with a silver-containing precursor in formic acid and in supercritical carbon dioxide. A procedure allowing the precursor reduction to silver nanoparticles both throughout the volume by thermal annealing of the films in the temperature interval 100–150°С and in the targeted mode using lasers operating at 405 and 532 nm was developed. It opens prospects for developing a process for production of heatresistant optical gratings and light guides. The reduces nanoparticles and their agglomerates have the size in the interval 50–200 nm and give a plasmon band in the range 450–460 nm.
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Original Russian Text © A.A. Akovantseva, N.A. Aksenova, T.S. Zarkhina, L.I. Krotova, N.V. Minaeva, А.О. Rybaltovskii, B.Ch. Kholkhoev, I.A. Farion, V.I. Yusupov, V.F. Burdukovskii, V.N. Bagratashvili, P.S. Timashev, 2017, published in Zhurnal Prikladnoi Khimii, 2017, Vol. 90, No. 1, pp. 91−97.
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Akovantseva, A.A., Aksenova, N.A., Zarkhina, T.S. et al. Preparation and optical properties of composite materials based on polybenzimidazole and silver nanoparticles. Russ J Appl Chem 90, 84–90 (2017). https://doi.org/10.1134/S107042721701013X
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DOI: https://doi.org/10.1134/S107042721701013X