Skip to main content
Log in

Synthesis, characterization, and controlled release study of polyurea microcapsules containing metribuzin herbicide

  • Various Technological Processes
  • Published:
Russian Journal of Applied Chemistry Aims and scope Submit manuscript

Abstract

Controlled release herbicide formulation was prepared by microencapsulation using interfacial polymerization technique. Methylene bisdiphenyl diisocynate (MDI) based polyuria as shell wall material containing mertribuzin herbicide as a core moiety has been prepared by an interfacial polycondensation reaction in emulsion globules between diisocyanate and ethylene diamine.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Kjaer, J., Olsen, P., Henriksen, J., and Ullum, M., J. Environ. Sci. Technol., 2005, vol. 39, pp. 8374–8381.

    Article  CAS  Google Scholar 

  2. Monitoring Ground Water for Pesticides. In Evaluation of Pesticides in Ground Water, Garner, W.Y., Honeycutt, R.C., and Nigg, H.N., Eds., Washington: American Chemical Society, 1986.

  3. Marc, G.M., Hanife, A., Nesrin, H., Debra, J.T., Joseph, D.G., and Donald, L., Resour. Conserv. & Recycle, 1996, vol. 16, pp. 289–320.

    Article  Google Scholar 

  4. Takayuki, T., Masahiro, Y., Kazumi, Y., Yasuo, H., Kouichiro, S., and Shiro, K., Polym. Bull., 2008, vol. 61, pp. 119–127.

    Article  CAS  Google Scholar 

  5. Declan, B., Theresa, K., and Andy, C., Environ. Pollut., 2005, vol. 133, pp. 85–90.

    Article  CAS  Google Scholar 

  6. Tsuji, K., J. Microencapsul., 2001, vol. 18, pp. 137–141.

    Article  CAS  Google Scholar 

  7. Hirech, K., Payan, S., Carnelle, G., Brujes, L., and Legrand, J., Powder Technol., 2003, vol. 130, pp. 324–329.

    Article  CAS  Google Scholar 

  8. Dowler, C.C., Dailey, O.D., and Mullinix, B.G., J. Agric Food Chem., 1999, vol. 47, pp. 2908–2913.

    Article  CAS  Google Scholar 

  9. Knowles, A., Environmentalist, 2008, vol. 28, pp. 35–44.

    Article  Google Scholar 

  10. Schwartz, L., Wolf, D., Markus, A., Wybraniec, S., and Wiesman, Z., J. Agric. Food Chem., 2003, vol. 51, pp. 5972–5976.

    Article  CAS  Google Scholar 

  11. Quaglia, F., Barbato, F., Rosa, G., Granata, E., Miro, A., and Rotonda, M., J. Agric. Food Chem., 2001, vol. 49, pp. 4808–4812.

    Article  CAS  Google Scholar 

  12. Undabeytia, T., Mishael, Y., Nir, S., Papahadjopoulos, D., Rubin, B., Morillo, E., and Maqueda, C., Environ. Sci. Technol., 2003, vol. 3, pp. 4475–4480.

    Article  CAS  Google Scholar 

  13. Garrido-Herrera, F.J., Gonzalez-Pradas, E., and Fernandez-Perez, M.J., J. Agric. Food Chem., 2006, vol. 54, pp. 10053–10060.

    Article  CAS  Google Scholar 

  14. Hekmat, A., Barati, A., Frahani, E., and Afraz, A., World Acad. of Sci. Eng. Technol., 2009, vol. 56, pp. 96–101.

    Google Scholar 

  15. Celis, R., Hermosin, M., Carrizosa, M., and Cornejo, J., J. Agric. Food Chem., 2002, vol. 6, pp. 2324–2330.

    Article  CAS  Google Scholar 

  16. Roy, A., Bajpai, J., and Bajpai, A.K., Ind. J. Chem. Technol., 2009, vol. 16, 388–395.

    CAS  Google Scholar 

  17. Knowles, A., Microencapsulation (CS). New Developments in Crop Protection Product Formulation, New York: Taylor and Francis/Informa UK, Ltd., 2005, pp. 89–114.

    Google Scholar 

  18. Yeom, C.K., Kim, Y.H., and Lee, J.M., J. Appl. Poly. Sci., 2002, vol. 84, pp. 1025–1034.

    Article  CAS  Google Scholar 

  19. Sopena, F., Maqueda, C., and Morillo, E., Cien. Inv. Agr., 2009, vol. 35, pp. 27–42.

    Google Scholar 

  20. Puoci, F., Iemma, F., Spizzirri, U., and Cirillo, G., J. Agri. Bio. Sci., 2008, vol. 3, pp. 299–314.

    Article  Google Scholar 

  21. Zhu, L., Wang, Z., Zhang, S., and Long, X., J. Pestic. Sci., vol. 35, pp. 339–343, 2010.

    Article  CAS  Google Scholar 

  22. Takahashi, Y., Taguchi, and Tanaka, M., J. Appl. Polym. Sci., 2008, vol. 107, pp. 2000–2006.

    Article  CAS  Google Scholar 

  23. Hedaoo, R.K., Tatiya, P.D., Mahulikar, P.P., and Gite, V.V., Desig. Mono and Poly, 2014, vol. 17, pp. 111–125.

    Article  CAS  Google Scholar 

  24. Scarfato, P., Avallone, E., Iannelli, P., Feo, V., and Acierno, D., J. Appl. Poly. Sci., 2007, vol. 105, pp. 3568–3577.

    Article  CAS  Google Scholar 

  25. Dailey, O.D., Dowler, C.C., and Mullinix, B.G., J. Agric. Food Chem., 1993, vol. 41, pp. 1517–1522.

    Article  CAS  Google Scholar 

  26. Ahmed, R., Ahmed, A., and Maisa, M., J. Polym. Sci. Part A: Polym. Chem., 2002, vol. 40, pp. 2513–2525.

    Article  CAS  Google Scholar 

  27. Pepperman, A.B., Kuan, J., and McCombs, C., J. Controlled Release, 1991, vol. 17, pp. 105–112.

    Article  CAS  Google Scholar 

  28. Sagiria, S.S., Sethya, J., Pala, K., Banerjeeb, I., Pramanik, K., and Maiti, T.K., Des. Monomers Polym., 2013, vol. 16, pp. 366–376.

    Article  CAS  Google Scholar 

  29. Rodrigues, S.N., Rodrigues, A.E., Fernandes, I., Martins, I.M., Mata, V.G., and Barreiro, F., Ind. Eng. Chem. Res., 2008, vol. 47, pp. 4142–4147.

    Article  CAS  Google Scholar 

  30. Reddy, C.L., Swamy, B.Y., Prasad, C., Rao, K., Prabhakar, M., Aswini, C., Subha, M., and Rao, K., Int. J. Polym. Mater. Polym. Biomater., 2012, vol. 61, pp. 424–436.

    Article  CAS  Google Scholar 

  31. Yang, J., Keller, M.W., Moore, J.S., White, S.R., and Sottos, N.R., Macromol., 2008, vol. 41, pp. 9650–9655.

    Article  CAS  Google Scholar 

  32. Jadhav, R.S., Hundiwale, D.G., and Mahulikar, P.P., J. Appl. Polym. Sci., 2011, vol. 119, pp. 2911–2916.

    Article  CAS  Google Scholar 

  33. Li, G., Feng, Y., Gao, P., and Li, X., Polym. Bull., 2008, vol. 60, pp. 725–731.

    Article  CAS  Google Scholar 

  34. Xinwu, B.A., Puying, A.N., Shuang, L.U., and Guangtian, L., Chin. J. Chem., 2009, vol. 27, pp. 1153–1158.

    Article  Google Scholar 

  35. Tutunaru, B., Samide, A., Moanta, A., Ionescu, C. and Tigae, C., Int. J. Electrochem. Sci., 2015, vol. 10, pp. 223–234.

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Dhananjay H. More.

Additional information

The text was submitted by the author in English.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Patil, D.K., Agrawal, D.S., Mahire, R.R. et al. Synthesis, characterization, and controlled release study of polyurea microcapsules containing metribuzin herbicide. Russ J Appl Chem 88, 1692–1700 (2015). https://doi.org/10.1134/S1070427215100225

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070427215100225

Keywords

Navigation