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Comparison of electronegativities of groups of certain organic and inorganic molecules

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Abstract

For functional groups containing oxygen and sulfur atoms qualitative relationships were obtained and a row of electronegativities was set up within the limits of the “quantum theory of atoms in molecules.” Possibilities of forecasting composition-property correlations on a specified basis were discussed.

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References

  1. Mezey, P.G., Mol. Phys., 1999, vol. 96, pp. 169–178.

    Article  CAS  Google Scholar 

  2. Hohenberg, P. and Kohn, W., Phys. Rev., 1964, vol. B136, pp. 864–871.

    Article  Google Scholar 

  3. Vereshchagin, A.N., Induktivnyi effect (Inductive Effect), Moscow: Nauka, 1987.

    Google Scholar 

  4. Pauling, L., The Nature of the Chemical Bond, New York: Cornell Univ. Press, 1960.

    Google Scholar 

  5. Cherkasov, A.R., Galkin, V.I., Zueva, E.M., and Cherkasov, R.A. Usp. Khim., 1998, vol. 67, no. 5, pp. 423–441.

    CAS  Google Scholar 

  6. Batsanov, S.S., Elektrootritsatel’nost’ elementov i khimicheskaya svyaz’ (Electronegativity of Elements and Chemical Bond), Novosibirsk: SO AN SSSR, 1962.

    Google Scholar 

  7. Volovik, S.V., Staninets, V.I., and Zefirov, N.S., Dokl. Akad. Nauk, 1993, vol.330, no. 3, pp. 321–323.

    CAS  Google Scholar 

  8. Urusov, V.S., Zh. Prikl. Khim., 1994, vol. 35, no. 1, pp. 111–127.

    CAS  Google Scholar 

  9. Sirotkin, O.S., Trubacheva, A.M., and Ivanova, S.N., Abstracts of Papers, VII Mezhdunarodnaya konferentsiya SevKavGTU, Stavropol, 2005, vol. 2, pp. 54–59.

    Google Scholar 

  10. Pankratov, A.N. and Shchavelev, A.E., Zh. Strukt. Khim., 1999, vol. 40, no. 6, pp. 1059–1066.

    Google Scholar 

  11. Benson, S.W., Thermochemical Kinetics. Methods for the Estimation of Thermochemical Date and Rate Parameters, New York: Wiley, 1968.

    Google Scholar 

  12. Tatevskii, V.M., Kvantovaya mekhanika i teoriya stroeniya molekul (Quantum Mechanics and the Theory of Structure of Molecules), Moscow: MGU, 1965.

    Google Scholar 

  13. Flygare, W.H., Molecular Structure and Dynamics, New York: Prentice-Hall, 1978.

    Google Scholar 

  14. Pankratov, A.N., Electronic Structure and Reactivity of Inorganic, Organic, Organoelement and Coordination Compounds: an Experience in the Area of Applied Quantum Chemistry, New York: Nova Science Publishers, Inc., 2007.

    Google Scholar 

  15. Cioslowski, J. and Mixon, S.T., J. Am. Chem. Soc., 1993, vol. 115, no. 3, pp. 1084–1088.

    Article  CAS  Google Scholar 

  16. Turovtsev, V.V., Orlov, Yu.D., and Lebedev, Yu.A., Zh. Fiz. Khim., 2009, vol. 83, no. 2, pp. 313–321.

    Google Scholar 

  17. Turovtsev, V.V. and Orlov, Yu.D., Zh. Fiz. Khim., 2010, vol. 84, no. 6, pp. 1074–1080.

    Google Scholar 

  18. Turovtsev, V.V. and Orlov, Yu.D., Zh. Fiz. Khim., 2010, vol. 84, no. 7, pp. 1296–1303.

    Google Scholar 

  19. Frisch, M.J., Trucks, G.W., Schlegel, H.B. et al., Gaussian 03 (Revision E 0.1), Gaussian Inc., Pittsburgh PA, 2007.

    Google Scholar 

  20. Bader, R.F.W., Atoms in Molecules. A Quantum Theory, Oxford: Clarendon press, 1999.

    Google Scholar 

  21. AIMAll (Version 09.10.24, Standard). Todd A. Keith, 2010. (http: // aim.tkgristmill.com).

Download references

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Original Russian Text © N.P. Rusakova, V.V. Turovtsev, Yu.D. Orlov, 2011, published in Zhurnal Prikladnoi Khimii, 2011, Vol. 84, No. 9, pp. 1578–1580.

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Rusakova, N.P., Turovtsev, V.V. & Orlov, Y.D. Comparison of electronegativities of groups of certain organic and inorganic molecules. Russ J Appl Chem 84, 1626 (2011). https://doi.org/10.1134/S1070427211090291

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  • DOI: https://doi.org/10.1134/S1070427211090291

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