Skip to main content
SpringerLink
Log in

Extractive recovery of gallium(III) from acid sulfate solutions with primary amines

  • Inorganic Synthesis And Industrial Inorganic Chemistry
  • Published:
Russian Journal of Applied Chemistry Aims and scope Submit manuscript

Abstract

Liquid extraction of Ga(III) ions with technical-grade aliphatic amines from sulfate media at a temperature of 20 ± 5°C was studied. The composition of the complex being extracted was determined and the equation of the reaction of Ga(III) extraction with primary amines was derived. The equilibrium constant of the reaction of gallium(III) extraction from acid sulfate solutions was found.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Reznik, A.M., Ponomareva, E.I., Silaev, Yu.N., et al., Protsessy ekstraktsii i sorbtsii v khimicheskoi tekhnologii galliya (Sorption and Extraction Processes in Chemical Technology of Gallium), Alma-Ata: Nauka, 1985.

    Google Scholar 

  2. Good, M.L., Bryan, S.E., and Frank Juge, J. Inorg. Chem., 1963, vol 2, no. 5, p. 963.

    Article  CAS  Google Scholar 

  3. Bina Gupta, Niti Mudhar, Zareena Begum I, and Indu Singh, Hydrometallurgy, 2007, vol. 87, nos. 1–2, p. 18.

    Google Scholar 

  4. Pawar, S.D. and Dhadke, P.M., J. Serb. Chem. Soc., 2003, vol.. 68, no. 7, p. 581.

    Article  CAS  Google Scholar 

  5. Turanov, A.N., Evseeva, N.K., and Karepov, B.R., Zh. Prikl. Khim., 2001, vol. 74. no. 8, pp. 1269–1273.

    Google Scholar 

  6. Rodriguez De San Miguel, E., Aguilar, J.C., Rodriguez, M.T.J., and De Gyves, J., Hydrometallurgy, 2000, vol. 57, no. 2, p. 151.

    Article  CAS  Google Scholar 

  7. Vainarovskaya, G.I., Gavrilov, N.I., Reznik, A.M., et al., Izv. Vyssh. Uchebn. Zaved., Tsv. Metall., 1977. no. 4, p. 84.

  8. Spravochnik po ekstraktsii (Handbook of Extraction), vol. 3, Rozen, A.M., Ed., Moscow: Atomizdat, 1978.

    Google Scholar 

  9. Shmidt, V.S., Ekstraktsiya aminami (Extraction with Amines), Moscow: Atomizdat, 1980.

    Google Scholar 

  10. Shevchuk, I.A. and Dubchenko, Yu.G., Available from ONIITEKhIM, 1974, Moscow, no. 164/74.Dep.

  11. Busev, A.I., Tiptsova, V.G., and Ivanov, V.M., Rukovodstvo po analiticheskoi khimii redkikh elementov (Manual of Analytical Chemistry of Rare Elements), Moscow: Khimiya, 1978, 2ng ed.

    Google Scholar 

  12. Shorikov, Yu.S., Orlov, A.M., and Sinitsyn, N.M., Khimiya ekstraktsii (Chemistry of Extraction), Novosibirsk: Nauka, 1984, pp. 149–161.

    Google Scholar 

  13. Nakamoto, K., Infrared Spectra of Inorganic and Coordination Compounds, New York: John Wiley & Sons, 1963.

    Google Scholar 

  14. Tananaev, I.V. and Bol’shakova, N.K., Zh. Neorg. Khim., 1962, vol. 7, no. 9, p. 2241.

    CAS  Google Scholar 

  15. Shishkova, L.G., Dokl. Bolg. Akad. Nauk, 1980, vol. 33 no. 6, p. 815.

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Chemical Problems, National Academy of Sciences of Azerbaijan, Baku, Azerbaijan

    A. A. Geidarov

Authors
  1. A. A. Geidarov
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Original Russian Text © A.A. Geidarov, 2008, published in Zhurnal Prikladnoi Khimii, 2008, Vol. 81, No. 12, pp. 1971–1974.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Geidarov, A.A. Extractive recovery of gallium(III) from acid sulfate solutions with primary amines. Russ J Appl Chem 81, 2084–2087 (2008). https://doi.org/10.1134/S1070427208120070

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070427208120070

Keywords

Search

Navigation