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Ferrocene Macrocyclic Schiff Base Complex: Synthesis, Structure and Recognition Properties for Dual Hg2+ and Cu2+

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Abstract

A probe based on ferrocene structure has been designed, synthesized and elucidated from the single crystal X-ray method. It demonstrated fluorescence response to Hg2+ and Cu2+ in CH3OH. The results indicated that the title complex could be applied in the multianalyte detection. Binding ability of receptor 3 in CH3OH was tested for various cations (Fe3+, Co2+, Cu2+, Zn2+, Cd2+, Hg2+, Pb2+, and Ba2+ in water). The computed binding constants for Hg2+ and Cu2+ indicated a distinct absorbance shift. The receptor is an attractive array due to its distinct absorbance shift profile in a semi-aqueous phase, making it applicable in biology, environmental sciences and material chemistry.

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References

  1. Ermakova, E., Michalak, J., Meyer, M., Arslanov, V., Tsivadze, A., and Guilard, R., Org. Lett., 2013, vol. 15, p. 662. doi 10.1021/ol303499v

    Article  CAS  Google Scholar 

  2. Schmidtchen, F.P. and Berger, M., Chem. Rev., 1997, vol. 97, p. 1609. doi 10.1021/cr9603845

    Article  CAS  Google Scholar 

  3. Beer, P.D. and Gale, P.A., Angew. Chem. Int. Ed., 2001, vol. 40, p. 486. doi 10.1002/1521-3773(20010202) 40:3<486::AID-ANIE486>3.0.CO;2-P

    Article  CAS  Google Scholar 

  4. Vicente, M.C., Burguete, M.I., Galindo, F., Izquierdo, M.A., Kumar, D.K., and White, A.J., J. Org. Chem., 2012, vol. 77, p. 490. doi 10.1021/jo202077v

    Article  Google Scholar 

  5. Jin, C., Zhang, M., Deng, C., Guan, Y.F., Gong, J., and Zhu, D.R., Tetrahedron. Lett., 2013, vol. 54, p. 796. doi 10.1016/j.tetlet.2012.11.117

    Article  CAS  Google Scholar 

  6. Kondo, S.I., Bie, Y., and Yamamura, M., Org. Lett., 2013, vol. 15, p. 520. doi 10.1021/ol303332k

    Article  CAS  Google Scholar 

  7. Chandra, B., Mahanta, S.P., Pati, N.N., Baskaran, S., Kanaparthi, R.K., and Sivasankar, C., Org. Lett., 2013, vol. 15, p. 306. doi 10.1021/ol3032158

    Article  CAS  Google Scholar 

  8. Wei, T.B., Zhang, P., Shi, B.B., Chen, P., Lin, Q., Liu, J., and Zhang. Y.M., Dyes Pigm., 2013, vol. 97, p. 297. doi 10.1016/j.dyepig.2012.12.025

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Key Laboratory of Synthetic and Natural Chemistry of the Ministry of Education, Chemical Engineering Institute, Yu-Lin University of Yulin, Chongwen av. 4, Yulin, Shaanxi Province, 719000, China

    Xiaoju Liu, Yulin Xiang, Xiangrong Ma, Guoyu Ren & Liguo Gao

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  1. Xiaoju Liu
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  2. Yulin Xiang
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  3. Xiangrong Ma
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  4. Guoyu Ren
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  5. Liguo Gao
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Correspondence to Xiaoju Liu.

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The text was submitted by the authors in English.

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Liu, X., Xiang, Y., Ma, X. et al. Ferrocene Macrocyclic Schiff Base Complex: Synthesis, Structure and Recognition Properties for Dual Hg2+ and Cu2+. Russ J Gen Chem 87, 2986–2988 (2017). https://doi.org/10.1134/S1070363217120428

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  • DOI: https://doi.org/10.1134/S1070363217120428

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