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Thermal properties of ligands, salts and metal complexes of linear oligopyrroles

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Abstract

The effect of structure on the thermal properties of dipyrrolylmethanes, dipyrrolylmethenes, bis (dipyrrolylmethenes), their salts, and chelates is analyzed proceeding from the results of thermogravimetric analysis. The common tendency is a decrease in the thermal stability of compounds with a disturbed symmetry of alkyl substitution of ligands and with a higher degree of their alkylation, with the increased size of alkyl substituents, with the nitrogen atom in the five-member cycles replaced by S or O. The opposite effect occurs at the change in the mode of attaching methylene spacer in going from 2,2′- to 3,3′-bis(dipyrrolylmethenes). The effects of the themostabilization of the ligands of linear oligopyrroles in the composition of chelates and HBr salts are evaluated quantitatively.

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References

  1. Loudet, A. and Burgess, K., Chem. Rev, 2007, vol. 107, p. 4891.

    Article  CAS  Google Scholar 

  2. Chepelev, L.L., Beshara, C.S., MacLean, P.D., Hatfield, G.L., Rand, A.A., Thompson, A., Wright, J.S., Barclay, L., and Ross, C., J. Org. Chem., 2006, vol. 71, p. 22.

    Article  CAS  Google Scholar 

  3. Wood, E. and Thompson, A., Chem. Rev., 2007, vol. 107, p. 1831.

    Article  CAS  Google Scholar 

  4. Killoran, J., Allen, L., Gallagher, J.F., Gallagher, W.M., and O’shea, D.F., Chem. Commun., 2002, p. 1862.

  5. Antina, E.V., Rumyantsev, E.V., Guseva, G.B., and Berezin, M.B., Uspekhi khimii porfirinov (Progress in Porphirin Chemistry), St. Petersburg State Univ., 2007, vol. 5, p. 148.

    Google Scholar 

  6. Rumyantsev, E.V., Guseva, G.B., and Antina, E.V., Zh. Fiz. Khim., 2005, vol. 79, no. 2, p. 219.

    Google Scholar 

  7. Guseva, G.B., Antina, E.V., Semeikin, A.S., Berezin, M.B., and Vyugin, A.I., J. Phys. Chem., 2006, vol. 80, no. 1, p. S98.

    CAS  Google Scholar 

  8. Guseva, G.B., Antina, E.V., and Vyugin, A.I., J. of Thermal Analysis and Calorimetry, 2008, vol. 92, no. 3, p. 735.

    Article  CAS  Google Scholar 

  9. Antina, E.V., Berezin, M.B., Guseva, G.B., Rumyantsev, E.V., and Balantseva, E.V., Collection of Publications, “Chemistry of Solutions and Technology of Liquid Phase Materials. Progress and Perspectives,” Institute of Solutions Chemistry, Russ. Acad. Sci., 2006, p. 105.

  10. Guseva, G.B., Antina, E.V., Semeikin, A.S., Berezin, M.B., and V’yugin, A.I., Zh. Obshch. Khim., 2002, vol. 72, no. 8, p. 1391.

    Google Scholar 

  11. Lebedeva, N.Sh., Antina, E.V., Berezin, M.B., Semeikin, A.S., and Bukushina, G.B., Zh. Fiz. Khim., 2000, vol. 74, no.7, p. 1165.

    CAS  Google Scholar 

  12. Semeikin, A.S., Berezin, M.B., Chernova, O.M., Antina, E.V., Syrbu, S.A., Lyubimova, T.V., and Kutepov, A.M., Izv. Akad. Nauk, Ser. Khim., 2003, no. 8, p. 1712.

  13. Rumyantsev, E.V., Guseva, G.B., Antina, E.V., Berezin, M.B., Sheinin, V.B., and V’yugin, A.I., Zh. Obshch. Khim., 2006, vol. 76, no. 1, p. 143.

    Google Scholar 

  14. Chernova, O.M., Berezin, M.B., and Antina, E.V., Zh. Fiz. Khim., 2003, vol. 77, no. 6, p. 1002.

    CAS  Google Scholar 

  15. Rumyantsev, E.V., Antina, E.V., and Berezin, M.B., Zh. Fiz. Khim., 2006, vol. 80, no. 7, p. 1244.

    Google Scholar 

  16. Rumyantsev, E.V. and Antina, E.V., Zh. Obshch. Khim., 2007, vol. 77, no. 8, p. 1363.

    Google Scholar 

  17. Comprehensive Organic Chemistry, Barton, D. and Ollis, W.D., Eds., Moscow: Khimiya, 1985, vol. 8, p. 332.

    Google Scholar 

  18. Semeikin, A.S. and Berezin, M.B., Uspekhi khimii porfirinov (Progress in Porphirin Chemistry), St. Petersburg State Univ., 2004, vol. 4, p. 7.

    Google Scholar 

  19. Falk, N., The Chemistry of Linear Oligopyrroles and Bile Pigments, New York: 1989.

  20. Mironov, A.F., Biosintez tetrapirrol’nykh pigmentov (Biosynthesis of Tetrapyrrol Pigments), Sorovskii Obrazovat. Zh., 1998, no. 7, p. 32.

  21. Berezin, B.D., Koordinatsionnye soedineniya porfirinov i ftalotsianina (Coordination Compounds of Porphirin and Phthalocyanines), Moscow: Nauka, 1978.

    Google Scholar 

  22. Mamardashvili, N.Zh. and Golubchikov, O.A., Usp. Khim., 2001, vol. 70, no. 7, p. 656.

    Google Scholar 

  23. Guseva, G.B., Dudina, N.A., Antina, E.V., V’yugin, A.I., and Semeikin, A.S., Zh. Obshch. Khim., 2008, vol. 78, no. 6, p. 987.

    Google Scholar 

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Authors and Affiliations

  1. Institute of Chemistry of Solutions, Russian Academy of Sciences, ul. Akademicheskaya 1, Ivanovo, 153045, Russia

    E. V. Antina, G. B. Gusev & N. A. Dudina

  2. Ivanovo State Chemical Engineering University, Ivanovo, Russia

    E. V. Antina, G. B. Gusev & E. V. Rumyantsev

Authors
  1. E. V. Antina
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  2. G. B. Gusev
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  3. E. V. Rumyantsev
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  4. N. A. Dudina
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Correspondence to E. V. Antina.

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Original Russian Text © E.V. Antina, G.B. Gusev, E.V. Rumyantsev, N.A. Dudina, 2009, published in Zhurnal Obshchei Khimii, 2009, Vol. 79, No. 9, pp. 1543–1552.

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Antina, E.V., Gusev, G.B., Rumyantsev, E.V. et al. Thermal properties of ligands, salts and metal complexes of linear oligopyrroles. Russ J Gen Chem 79, 1900–1909 (2009). https://doi.org/10.1134/S1070363209090163

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  • DOI: https://doi.org/10.1134/S1070363209090163

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