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Structural parameters of hydration of Be2+ and Mg2+ ions in aqueous solutions of their salts

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Abstract

Published data on structural characteristics of hydration of beryllium and magnesium ions in aqueous solutions of their salts under standard conditions, obtained by various methods, as well as authors’ X-ray data are reviewed. Structural parameters of the immediate environment of Be2+ and Mg2+, specifically coordination numbers, interparticle distances, and types of ionic association, are discussed. It is noted that Be2+ coordinates four water molecules at an average distance of 0.167 nm and Mg2+ coordinates six water molecules at an average distance of 0.210 nm. In aqueous solutions of their salts, both Be2+ and Mg2+ form the second coordination spheres.

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Authors and Affiliations

  1. Institute of Solution Chemistry, Russian Academy of Sciences, ul. Akademicheskaya 1, Ivanovo, 153045, Russia

    P. R. Smirnov & V. N. Trostin

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  1. P. R. Smirnov
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  2. V. N. Trostin
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Correspondence to P. R. Smirnov.

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Original Russian Text © P.R. Smirnov, V.N. Trostin, 2008, published in Zhurnal Obshchei Khimii, 2008, Vol. 78, No. 9, pp. 1409–1416.

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Smirnov, P.R., Trostin, V.N. Structural parameters of hydration of Be2+ and Mg2+ ions in aqueous solutions of their salts. Russ J Gen Chem 78, 1643–1649 (2008). https://doi.org/10.1134/S1070363208090016

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