Abstract
Magnetic susceptibility and electrophysical properties of copper-containing solid solutions of the low-temperature modification of bismuth orthoniobate were studied. Parameters of exchange interactions in dimeric copper clusters and distribution of monomers and dimers in the solutions were calculated. The exchange parameter of antiferromagnetic interactions in dimeric copper clusters was found to be 170 cm−1.
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Zhuk, N.A., Piir, I.V., and Chezhina, N.V., Zh. Obshch. Khim., 2006, vol. 76, no. 11, p. 1786.
Popolitov, V.I., Neorg. Mater., 1990, vol. 26, no. 2, p. 362.
Huang, C., Weng, M., and Yu, C., Ceramics Int., 2001, vol. 27, p. 343.
Tzou, W., Yang, C., Chen, Y., and Cheng, P., J. Eur. Ceram. Soc., 2000, vol. 20, p. 991.
Wang, N., Zhao, M., Yin, Z., and Li, W., Mater. Res. Bull., 2004, vol. 39, p. 439.
Yang, Y., Ding, S., and Yao, X., Ceramics Int., 2004, vol. 30, p. 1335.
Shihua, D., Yao, X., and Yong, Y., Ceramics Int., 2004, vol. 30, p. 1195.
Yang, Y., Ding, S., and Yao, X., Ceramics Int., 2004, vol. 30, p. 1341.
Subramanian, A.K. and Calabresse, J.C., Mater. Res. Bull., 1993, vol. 28, p. 523.
Akselrud, L.G., Gryn, Y.N., and Zavaltij, P.Yu., Abstracts of Papers, 12th Eur. Crystallogr. Meeting, 1985, p. 55.
Kalinnikov, V.T. and Rakitin, Yu.V., Vvedenie v magnetokhimiyu. Metod staticheskoi magnitnoi vospriimchivosti (Introduction to Magnetochemistry. Method of Static Magnetic Susceptibility), Moscow: Nauka, 1980.
Sych, A.M., Popolitov, V.I., and Eremenko, L.A., Zh. Neorg. Khim., 1975, vol. 20, no. 10, p. 2605.
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Original Russian Text N.A. Zhuk, I.V. Piir, N.V. Chezhina, 2007, published in Zhurnal Obshchei Khimii, 2007, Vol. 77, No. 2, pp. 240–245.
For communication II, see [1].
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Zhuk, N.A., Piir, I.V. & Chezhina, N.V. Structure and magnetic and electric properties of bismuth niobates doped with d-elements: III. Magnetic and electric properties of copper-containing solid solutions of bismuth orthoniobate. Russ J Gen Chem 77, 215–220 (2007). https://doi.org/10.1134/S1070363207020053
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DOI: https://doi.org/10.1134/S1070363207020053