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On the Reactivity and Stability of Iodide–Nitride–Sulfide Clusters of Neodymium and Dysprosium

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Abstract

The thermal decomposition of cluster Nd3I5(S2)(S2N2)(THF)10 (I) at 50–400°C affords a mixture of products among which tetrahydrofuran (THF), sulfur, diiodine, HI, H2S, CS2, S3N6, S3N5, MeI, thiophene, tetrahydrothiophene, diiodobutane, iodobutene, and NdI3 are identified. The treatment of Ln3I5(S2)(S2N2)(THF)10 (Ln = Nd (I), Dy (II)) with phenanthroline (Phen) in THF at room temperature results in the partial substitution of ТНF to form new complexes Ln3I5(S2)(S2N2)(THF)4(Phen)3. The dissolution of compound I in pyridine gives a pyridine (Py) complex Ln3I5(S2)(S2N2)(THF)3(Py)7. The dissolution of compounds I and II in acetonitrile at 20°C is accompanied by the fast rearrangement and fragmentation of the complexes to form LnI3(MeCN)6, [LnI(S2)(MeCN)], and [LnI(S2N2)(MeCN)]. Complex I in THF does not react with white phosphorus, carbon monoxide, fullerene C60, and chromium hexacarbonyl.

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Authors and Affiliations

  1. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, ul. Tropinina 49, Nizhny Novgorod, 603600, Russia

    A. A. Fagin, D. M. Kuzyaev, M. A. Burin, O. V. Kuznetsova, N. M. Khamaletdinova, T. I. Kulikova, T. I. Lopatina & M. N. Bochkarev

  2. Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow oblast, 142432, Russia

    A. F. Shestakov

  3. Lobachevsky National Research University, Nizhny Novgorod, Russia

    D. L. Vorozhtsov & M. N. Bochkarev

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  1. A. A. Fagin
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  2. D. M. Kuzyaev
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  3. M. A. Burin
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  4. O. V. Kuznetsova
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  5. N. M. Khamaletdinova
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  6. T. I. Kulikova
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  7. A. F. Shestakov
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  8. T. I. Lopatina
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  9. D. L. Vorozhtsov
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  10. M. N. Bochkarev
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Correspondence to O. V. Kuznetsova.

Additional information

Original Russian Text © A.A. Fagin, D.M. Kuzyaev, M.A. Burin, O.V. Kuznetsova, N.M. Khamaletdinova, T.I. Kulikova, A.F. Shestakov, T.I. Lopatina, D.L. Vorozhtsov, M.N. Bochkarev, 2018, published in Koordinatsionnaya Khimiya, 2018, Vol. 44, No. 1, pp. 38–42.

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Fagin, A.A., Kuzyaev, D.M., Burin, M.A. et al. On the Reactivity and Stability of Iodide–Nitride–Sulfide Clusters of Neodymium and Dysprosium. Russ J Coord Chem 44, 127–131 (2018). https://doi.org/10.1134/S1070328418020045

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  • DOI: https://doi.org/10.1134/S1070328418020045

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