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Syntheses and structures of tetraphenylantimony oximates: Ph4SbON=CHR (R = C6H4Br-2, C6H4NO2-2, C4H3S)

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Abstract

The reactions of pentaphenylantimony with oximes or triphenylantimony dioximates in toluene afford tetraphenylantimony oximates Ph4SbON=CHR (R = C6H4Br-2 (I), C6H4NO2-2 (II), and C4H3S-2 (III)). Triphenylantimony dioximates are synthesized by oxidative addition from triphenylantimony and oxime in diethyl ether in the presence of tert-butyl hydroperoxide. According to the X-ray diffraction data (CIF files CCDC no. 1055414 (I), 1055634 (II), and 1061727 (III)), the coordination mode of the antimony atoms in the molecules of compounds I–III is a distorted trigonal bipyramid with the oxygen atom of the oximate ligand in the axial position. The structural organization of the crystals is caused by weak hydrogen bonds.

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Authors and Affiliations

  1. National Research Southern Ural State University, Chelyabinsk, Russia

    V. V. Sharutin & O. K. Sharutina

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  1. V. V. Sharutin
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  2. O. K. Sharutina
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Correspondence to V. V. Sharutin.

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Original Russian Text © V.V. Sharutin, O.K. Sharutina, 2017, published in Koordinatsionnaya Khimiya, 2017, Vol. 43, No. 4, pp. 244–249.

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Sharutin, V.V., Sharutina, O.K. Syntheses and structures of tetraphenylantimony oximates: Ph4SbON=CHR (R = C6H4Br-2, C6H4NO2-2, C4H3S). Russ J Coord Chem 43, 232–237 (2017). https://doi.org/10.1134/S1070328417040054

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  • DOI: https://doi.org/10.1134/S1070328417040054

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