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Mixed ligand acetate, propionate, and pivalate complexes of rare earth metals with monoethanolamine: A new approach to the synthesis, composition, structure, and use for the preparation of oxide materials

  • The Issue is Devoted to Carboxylate Complexes of Transition Metals
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Abstract

Compositions of mixed ligand acetate, propionate, and pivalate complexes of rare earth metals of the cerium and yttrium groups with monoethanolamine are predetermined by the synthesis conditions and the nature of the carboxylate ligand and rare earth metal ion. Solid mixed ligand complexes [Ln(Piv)5(MEAH)][MEAH] and [Ln(Piv)3(MEA)], homoligand complexes [Ln(Piv)3] (HPiv is 2,2-dimethylpropionic (pivalic) acid), and gel-like hydroxo complexes [Ln(Carb)3–x–y (NO3) x -(OH) y (MEA) w (H2O) z ] (HCarb is acetic (HAc) or propionic (HProp) acid) are isolated using original synthesis procedures involving ion pairs [MEAH]+[Carb]– (MEA is monoethanolamine). The compounds are studied by IR spectroscopy, 1H NMR spectroscopy, elemental and thermal analyses, and mass spectrometry. Specific features for the complex formation of rare earth metal pivalates with MEA are additionally studied using quantum-chemical simulation.

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Authors and Affiliations

  1. Moscow State University, Moscow, 119991, Russia

    D. M. Tsymbarenko, I. A. Martynova & N. P. Kuzmina

  2. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia

    I. P. Malkerova & A. S. Alikhanyan

Authors
  1. D. M. Tsymbarenko
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  2. I. A. Martynova
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  3. I. P. Malkerova
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  4. A. S. Alikhanyan
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  5. N. P. Kuzmina
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Correspondence to D. M. Tsymbarenko.

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Original Russian Text © D.M. Tsymbarenko, I.A. Martynova, I.P. Malkerova, A.S. Alikhanyan, N.P. Kuzmina, 2016, published in Koordinatsionnaya Khimiya, 2016, Vol. 42, No. 10, pp. 624–639.

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Tsymbarenko, D.M., Martynova, I.A., Malkerova, I.P. et al. Mixed ligand acetate, propionate, and pivalate complexes of rare earth metals with monoethanolamine: A new approach to the synthesis, composition, structure, and use for the preparation of oxide materials. Russ J Coord Chem 42, 662–678 (2016). https://doi.org/10.1134/S1070328416100043

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  • DOI: https://doi.org/10.1134/S1070328416100043

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