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Synthesis, crystal structure, and properties of a new lanthanide tartrate coordination polymer

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Abstract

A new coordination polymer of terbium tartrate [Tb(H2O)3(C4H5O6)(C4H4O6)] has been synthesized and crystallizes in the polar space group P41 with cell constants a = 6.0415(9), b = 6.0415(9), c = 36.516(7) Å, V = 1332.8(4) Å3, Z = 4. The terbium(III) ion of title complex is nine-coordinate through oxygen donors. Four different coordination modes of tartrate occur. This Tb(III) complex exhibits a characteristic luminescence in the visible region upon excitation at 353 nm. The temperature-dependent magnetic properties of the Tb(III) complex were investigated in the temperature range of 2–300 K. Title compound exhibits significant ferroelectric properties at room temperature (remnant polarization 2P r = 0.160 μC cm−2, coercive field 2E c = 44.5 kV cm−1, saturation of the spontaneous polarization P s = 0.176 μC cm−2).

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Authors and Affiliations

  1. Center of Applied Solid State Chemistry Research Ningbo University, Ningbo, 315211, P.R. China

    W. Xu, H. S. Chang, W. Liu & Y. Q. Zheng

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  1. W. Xu
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  2. H. S. Chang
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  3. W. Liu
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  4. Y. Q. Zheng
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Correspondence to Y. Q. Zheng.

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Xu, W., Chang, H.S., Liu, W. et al. Synthesis, crystal structure, and properties of a new lanthanide tartrate coordination polymer. Russ J Coord Chem 40, 251–256 (2014). https://doi.org/10.1134/S1070328414030105

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  • DOI: https://doi.org/10.1134/S1070328414030105

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